Self-Assembly of Hybrid Organic−Inorganic Polyoxomolybdates: Solid-State Structures and Investigation of Formation and Core Rearrangements in Solution

2011 ◽  
Vol 50 (2) ◽  
pp. 604-613 ◽  
Author(s):  
Camelia I. Onet ◽  
Lei Zhang ◽  
Rodolphe Clérac ◽  
J. Bernard Jean-Denis ◽  
Martin Feeney ◽  
...  
Keyword(s):  
Solid State ◽  
Self Assembly ◽  
Solid State Structures

scholarly journals Exploring the Self-Assembled Tacticity in Aurophilic Polymeric Arrangements of Diphosphanegold(I) Fluorothiolates

Molecules ◽  
2019 ◽  
Vol 24 (23) ◽  
pp. 4422 ◽  
Author(s):  
Moreno-Alcántar ◽  
Salazar ◽  
Romo-Islas ◽  
Flores-Álamo ◽  
Torrens
Keyword(s):  
Solid State ◽  
Self Assembly ◽  
Structural Diversity ◽  
Supramolecular Structures ◽  
X Ray Diffraction ◽  
Ligand Effects ◽  
Rational Control ◽  
Solid State Structures ◽  
Further Development ◽  
Aurophilic Interactions

Despite the recurrence of aurophilic interactions in the solid-state structures of gold(I) compounds, its rational control, modulation, and application in the generation of functional supramolecular structures is an area that requires further development. The ligand effects over the aurophilic-based supramolecular structures need to be better understood. This paper presents the supramolecular structural diversity of a series of new 1,3-bis(diphenylphosphane)propane (dppp) gold(I) fluorinated thiolates with the general formula [Au2(SRF)2(μ-dppp)] (SRF = SC6F5 (1); SC6HF4-4 (2); SC6H3(CF3)2-3,5 (3); SC6H4CF3-2 (4); SC6H4CF3-4 (5); SC6H3F2-3,4 (6); SC6H3F2-3,5 (7); SC6H4F-2 (8); SC6H4F-3 (9); SC6H4F-4 (10)). These compounds were synthesized and characterized, and six of their solid-state crystalline structures were determined using single-crystal X-ray diffraction. In the crystalline arrangement, they form aurophilic-bridged polymers. In these systems, the changes in the fluorination patterns of the thiolate ligands tune the aurophilic-induced self-assembly of the compounds causing tacticity and chiral differentiation of the monomers. This is an example of the use of ligand effects on the tune of the supramolecular association of gold complexes.

Janus-AT Bases:  Synthesis, Self-Assembly, and Solid State Structures

2007 ◽  
Vol 72 (2) ◽  
pp. 466-475 ◽  
Author(s):  
Ali Asadi ◽  
Brian O. Patrick ◽  
David M. Perrin
Keyword(s):  
Solid State ◽  
Self Assembly ◽  
Solid State Structures

scholarly journals Appealing Copper(I) and Silver(I) Coordination Polymers with an Unprecedented Betainoid Assembling Ligand

2019 ◽  
pp. 24-28
Author(s):  
Dylan Amelot ◽  
Ammar Hassoun ◽  
Lise-Marie Chamoreau ◽  
Hani Amouri ◽  
Jamal Moussa
Keyword(s):  
Solid State ◽  
Single Crystal ◽  
Coordination Polymers ◽  
Elemental Analysis ◽  
Self Assembly ◽  
Spectroscopic Methods ◽  
Photoluminescence Properties ◽  
Single Crystal Diffraction ◽  
Coinage Metals ◽  
Solid State Structures

Two coordination polymers of coinage metals with a rare pyridinium-betainoid L assembling ligand are reported. These polymers are obtained by self-assembly of the linker L and copper(I) or silver(I) ions in acetonitrile. The compounds were characterized by spectroscopic methods and by elemental analysis. The solid-state structures were unambiguously confirmed by single crystal diffraction studies. These assemblies exhibit original helicoidal arrangements. The UV-Vis. absorption and photoluminescence properties are reported as well.

From Solid-State Structures and Superstructures to Self-Assembly Processes

1994 ◽  
Vol 6 (8) ◽  
pp. 1159-1167 ◽  
Author(s):  
David B. Amabilino ◽  
J. Fraser Stoddart ◽  
David J. Williams
Keyword(s):  
Solid State ◽  
Self Assembly ◽  
Solid State Structures

Trianionic calix[4]arene monoalkoxy derivatives: synthesis, solid-state structures and self-assembly properties

2008 ◽  
Vol 32 (11) ◽  
pp. 1988 ◽  
Author(s):  
Kinga Suwinska ◽  
Oleksandr Shkurenko ◽  
Cyrille Mbemba ◽  
Antoine Leydier ◽  
Said Jebors ◽  
...  
Keyword(s):  
Solid State ◽  
Self Assembly ◽  
Solid State Structures
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