Role of Orbital Degeneracy in the Single Molecule Magnet Behavior of a Mononuclear High-Spin Fe(II) Complex

2010 ◽  
Vol 49 (17) ◽  
pp. 8073-8077 ◽  
Author(s):  
A. V. Palii ◽  
J. M. Clemente-Juan ◽  
E. Coronado ◽  
S. I. Klokishner ◽  
S. M. Ostrovsky ◽  
...  
Keyword(s):  
High Spin ◽  
Single Molecule ◽  
Orbital Degeneracy ◽  
Single Molecule Magnet

scholarly journals A Co-based single-molecule magnet confined in a barium phosphate apatite matrix with a high energy barrier for magnetization relaxation

2017 ◽  
Vol 53 (39) ◽  
pp. 5416-5419 ◽  
Author(s):  
Pavel E. Kazin ◽  
Mikhail A. Zykin ◽  
Lev A. Trusov ◽  
Artem A. Eliseev ◽  
Oxana V. Magdysyuk ◽  
...  
Keyword(s):  
High Spin ◽  
Single Molecule ◽  
Energy Barrier ◽  
High Energy ◽  
Magnetization Relaxation ◽  
Single Molecule Magnet ◽  
High Energy Barrier ◽  
Spin Reversal ◽  
Type Lattice ◽  
Apatite Type

A Co-ion introduced into the trigonal channel of an apatite-type lattice forms a magnetically anisotropic two-coordinated Co-complex with a record-high spin-reversal energy barrier.

Role of the Orbitally Degenerate Mn(III) Ions in the Single-Molecule Magnet Behavior of the Cyanide Cluster {[MnII(tmphen)2]3[MnIII(CN)6]2} (tmphen = 3,4,7,8-tetramethyl-1,10-phenanthroline)

2004 ◽  
Vol 126 (51) ◽  
pp. 16860-16867 ◽  
Author(s):  
Andrei V. Palii ◽  
Sergei M. Ostrovsky ◽  
Sophia I. Klokishner ◽  
Boris S. Tsukerblat ◽  
Curtis P. Berlinguette ◽  
...  
Keyword(s):  
Single Molecule ◽  
Single Molecule Magnet

The role of coordinated solvent on Co(ii) ions in tuning the single molecule magnet properties in a {CoII2DyIII2} system

2017 ◽  
Vol 46 (16) ◽  
pp. 5337-5343 ◽  
Author(s):  
Yan Peng ◽  
Valeriu Mereacre ◽  
Christopher E. Anson ◽  
Annie K. Powell
Keyword(s):  
Single Molecule ◽  
Solvent Molecule ◽  
Coordination Geometry ◽  
Single Molecule Magnet ◽  
System P

The anisotropy of a single DyIII can be steered through subtle changes in the coordination geometry of the CoII ions in CoII2DyIII2 butterfly compounds resulting from changing the coordinated solvent molecule on the CoII ion.

High-Spin Cyclopentadienyl Complexes: A Single-Molecule Magnet Based on the Aryl-Iron(II) Cyclopentadienyl Type

2011 ◽  
Vol 17 (17) ◽  
pp. 4700-4704 ◽  
Author(s):  
Daniel Weismann ◽  
Yu Sun ◽  
Yanhua Lan ◽  
Gotthelf Wolmershäuser ◽  
Annie K. Powell ◽  
...  
Keyword(s):  
High Spin ◽  
Single Molecule ◽  
Single Molecule Magnet ◽  
Cyclopentadienyl Complexes

Systematic studies of hexanuclear {MIII4LnIII2} complexes (M = Fe, Ga; Ln = Er, Ho): structures, magnetic properties and SMM behavior

2017 ◽  
Vol 4 (6) ◽  
pp. 927-934 ◽  
Author(s):  
Sihuai Chen ◽  
Valeriu Mereacre ◽  
George E. Kostakis ◽  
Christopher E. Anson ◽  
Annie K. Powell
Keyword(s):  
Magnetic Properties ◽  
Single Molecule ◽  
Single Molecule Magnet

The first heterometallic GaIII–ErIII single-molecule magnet has been synthesized and the role of GaIII in extracting the FeIII–ErIII and ErIII–ErIII interaction has been assessed.

A Non‐sandwiched Macrocyclic Monolanthanide Single‐Molecule Magnet: The Key Role of Axiality

2011 ◽  
Vol 17 (16) ◽  
pp. 4362-4365 ◽  
Author(s):  
Humphrey L. C. Feltham ◽  
Yanhua Lan ◽  
Frederik Klöwer ◽  
Liviu Ungur ◽  
Liviu F. Chibotaru ◽  
...  
Keyword(s):  
Single Molecule ◽  
Single Molecule Magnet

“Spin Tweaking” of a High-Spin Molecule: An Mn25 Single-Molecule Magnet with anS=61/2 Ground State

2007 ◽  
Vol 46 (6) ◽  
pp. 884-888 ◽  
Author(s):  
Theocharis C. Stamatatos ◽  
Khalil A. Abboud ◽  
Wolfgang Wernsdorfer ◽  
George Christou
Keyword(s):  
High Spin ◽  
Single Molecule ◽  
Ground State ◽  
Single Molecule Magnet
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