Synthesis, Crystal Structure, and Characterization of a Heterometallic One-Dimensional Complex with Metal−Metal Bonds

Kazuhiro Uemura; Kôichi Fukui; Kana Yamasaki; Kazuko Matsumoto; Masahiro Ebihara

doi:10.1021/ic1004775

Synthesis, Crystal Structure, and Characterization of a Heterometallic One-Dimensional Complex with Metal−Metal Bonds

Inorganic Chemistry ◽

10.1021/ic1004775 ◽

2010 ◽

Vol 49 (16) ◽

pp. 7323-7330 ◽

Cited By ~ 18

Author(s):

Kazuhiro Uemura ◽

Kôichi Fukui ◽

Kana Yamasaki ◽

Kazuko Matsumoto ◽

Masahiro Ebihara

Keyword(s):

Crystal Structure ◽

One Dimensional ◽

Metal Metal ◽

Metal Metal Bonds ◽

Metal Bonds

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ChemInform Abstract: Luminescent Organometallic Compounds with Relativistic Metal-Metal Bonds. Synthesis and Characterization of AuTl(Ph2P(CH2)S)2, a One-Dimensional Metal-Metal Bonded Polymer in the Solid State.

ChemInform ◽

10.1002/chin.198836309 ◽

1988 ◽

Vol 19 (36) ◽

Author(s):

S. WANG ◽

J. P. JUN. FACKLER ◽

C. KING ◽

J. C. WANG

Keyword(s):

Solid State ◽

Organometallic Compounds ◽

Synthesis And Characterization ◽

One Dimensional ◽

Metal Metal ◽

Metal Metal Bonds ◽

Metal Bonds

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Luminescent organometallic compounds with relativistic metal-metal bonds. Synthesis and characterization of AuTl[Ph2P(CH2)S]2, a one-dimensional gold-thallium metal-metal bonded polymer in the solid state

Journal of the American Chemical Society ◽

10.1021/ja00218a055 ◽

1988 ◽

Vol 110 (10) ◽

pp. 3308-3310 ◽

Cited By ~ 39

Author(s):

Suning. Wang ◽

John P. Fackler ◽

C. King ◽

J. C. Wang

Keyword(s):

Solid State ◽

Organometallic Compounds ◽

Synthesis And Characterization ◽

One Dimensional ◽

Metal Metal ◽

Metal Metal Bonds ◽

Metal Bonds

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ChemInform Abstract: STEREOCHEMISTRY OF METAL-METAL BONDS- CRYSTAL STRUCTURE OF CR2(CO)7(C5H5)AS(CH3)2

Chemischer Informationsdienst ◽

10.1002/chin.197837101 ◽

1978 ◽

Vol 9 (37) ◽

Author(s):

E. ROETTINGER ◽

H. VAHRENKAMP

Keyword(s):

Crystal Structure ◽

Metal Metal ◽

Metal Metal Bonds ◽

Metal Bonds

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ChemInform Abstract: ORGANOMETALLIC COMPLEXES WITH METAL-METAL BONDS. 10. SYNTHETIC AND CRYSTAL STRUCTURE OF A PLANAR, TRIANGULATED COMBINED PALLADIUM-MOLYBDENUM

Chemischer Informationsdienst ◽

10.1002/chin.197846327 ◽

1978 ◽

Vol 9 (46) ◽

Author(s):

R. BENDER ◽

P. BRAUNSTEIN ◽

Y. DUSAUSOY ◽

J. PROTAS

Keyword(s):

Crystal Structure ◽

Organometallic Complexes ◽

Metal Metal ◽

Metal Metal Bonds ◽

Metal Bonds

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Acetamidate-bridged paddlewheel dirhodium complex sandwiched by mononuclear platinum complexes with axial metal–metal bonds affording neutral heterometallic one-dimensional alignments

Inorganica Chimica Acta ◽

10.1016/j.ica.2014.08.041 ◽

2015 ◽

Vol 424 ◽

pp. 194-201 ◽

Cited By ~ 8

Author(s):

Kazuhiro Uemura ◽

Tomofumi Yamada ◽

Toru Kanbara ◽

Masahiro Ebihara

Keyword(s):

Platinum Complexes ◽

One Dimensional ◽

Metal Metal ◽

Metal Metal Bonds ◽

Metal Bonds

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Metalloporphyrins with metal-metal bonds. Synthesis and characterization of (P)InMn(CO)5, (P)InCo(CO)4, and (P)InM(CO)3Cp where M = Cr, Mo, and W. Molecular stereochemistry of [(2,3,7,8,12,13,17,18-octaethylporphyrinato)indium(III)]pentacarbonylmanganese

Inorganic Chemistry ◽

10.1021/ic00262a026 ◽

1987 ◽

Vol 26 (15) ◽

pp. 2467-2476 ◽

Cited By ~ 17

Author(s):

R. Guilard ◽

P. Mitaine ◽

C. Moise ◽

C. Lecomte ◽

A. Boukhris ◽

...

Keyword(s):

Synthesis And Characterization ◽

Metal Metal ◽

Metal Metal Bonds ◽

Metal Bonds

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ChemInform Abstract: Weak Metal-Metal Bonds in an "Electron-Rich" Cluster. The Synthesis and X-ray Crystallographic Characterization of Os4(CO)12(μ3-S)2and Os6(CO)16(μ4-S)(μ3-S).

Chemischer Informationsdienst ◽

10.1002/chin.198244314 ◽

1982 ◽

Vol 13 (44) ◽

Author(s):

R. D. ADAMS ◽

L.-W. YANG

Keyword(s):

Rich Cluster ◽

X Ray ◽

Metal Metal ◽

Metal Metal Bonds ◽

Metal Bonds

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Spectral and Structural Characterization of Amidate-Bridged Platinum−Thallium Complexes with Strong Metal−Metal Bonds

Inorganic Chemistry ◽

10.1021/ic051678o ◽

2006 ◽

Vol 45 (11) ◽

pp. 4526-4536 ◽

Cited By ~ 40

Author(s):

Wanzhi Chen ◽

Fenghui Liu ◽

Kazuko Matsumoto ◽

Jochen Autschbach ◽

Boris Le Guennic ◽

...

Keyword(s):

Structural Characterization ◽

Metal Metal ◽

Metal Metal Bonds ◽

Metal Bonds

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ChemInform Abstract: ORGANOMETALLIC COMPLEXES WITH METAL-METAL BONDS. 14. SYNTHESIS AND CRYSTAL STRUCTURE OF A CHIRAL COMPLEX WITH NONLINEAR HETEROTRIMETAL CHAIN: PTMN2(μ2-PPH2)2(CO)9

Chemischer Informationsdienst ◽

10.1002/chin.198004068 ◽

1980 ◽

Vol 11 (4) ◽

Author(s):

P. BRAUNSTEIN ◽

D. MATT ◽

O. BARS ◽

D. GRANDJEAN

Keyword(s):

Crystal Structure ◽

Organometallic Complexes ◽

Synthesis And Crystal Structure ◽

Chiral Complex ◽

Metal Metal ◽

Metal Metal Bonds ◽

Metal Bonds

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Öffnung von Dreikernclustern durch Diphosphinomethan-Liganden / Opening of Trinuclear Clusters by Diphosphinomethane Ligands

Zeitschrift für Naturforschung B ◽

10.1515/znb-1989-0208 ◽

1989 ◽

Vol 44 (2) ◽

pp. 139-144 ◽

Cited By ~ 3

Author(s):

Roy P. Planalp ◽

Heinrich Vahrenkamp

Keyword(s):

Crystal Structure ◽

Structure Determination ◽

Addition Product ◽

Crystal Structure Determination ◽

Metal Metal ◽

Trinuclear Clusters ◽

Metal Metal Bonds ◽

Metal Bonds

Abstract The phosphinidene bridged clusters FeCo2(CO)9(PMe) and FeCoWCp(CO)8(PM e) add the diphosphinomethane ligands dmpm and dppm with concomitant opening of two metal-metal bonds. The crystal structure determination of the addition product (Me2P-CH2-PMe2)FeCoWCp(CO)8(PMe) has shown that the Fe -W and Fe -Co bonds have been opened and the chelating diphosphine spans the Co -W bond. This is in contrast to the reaction with monodentate phosphines where the Co -W and Co -Fe bonds are broken. Upon heating the addition products eliminate two moles of CO with formation of the diphos phinom ethane substituted starting clusters, which in turn add CO under pressure to re-form the addition products.

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