Electrical Conductivity and Spin Crossover:  A New Achievement with a Metal Bis Dithiolene Complex

2007 ◽  
Vol 46 (21) ◽  
pp. 8548-8559 ◽  
Author(s):  
Christophe Faulmann ◽  
Kane Jacob ◽  
Stéphane Dorbes ◽  
Stéphane Lampert ◽  
Isabelle Malfant ◽  
...  
Keyword(s):  
Electrical Conductivity ◽  
Spin Crossover

scholarly journals Electrical conductivity and magnetic bistability in metal–organic frameworks and coordination polymers: charge transport and spin crossover at the nanoscale

2020 ◽  
Vol 49 (15) ◽  
pp. 5601-5638 ◽  
Author(s):  
Víctor Rubio-Giménez ◽  
Sergio Tatay ◽  
Carlos Martí-Gastaldo
Keyword(s):  
Electrical Conductivity ◽  
Charge Transport ◽  
Coordination Polymers ◽  
Spin Crossover ◽  
Electronic Devices ◽  
Metal Organic Frameworks ◽  
Active Components ◽  
Metal Organic

This review aims to reassess the progress, issues and opportunities in the path towards integrating conductive and magnetically bistable coordination polymers and metal–organic frameworks as active components in electronic devices.

Evidence of the Chemical Uniaxial Strain Effect on Electrical Conductivity in the Spin-Crossover Conducting Molecular System: [FeIII(qnal)2][Pd(dmit)2]5·Acetone

2008 ◽  
Vol 130 (21) ◽  
pp. 6688-6689 ◽  
Author(s):  
Kazuyuki Takahashi ◽  
Heng-Bo Cui ◽  
Yoshinori Okano ◽  
Hayao Kobayashi ◽  
Hatsumi Mori ◽  
...  
Keyword(s):  
Electrical Conductivity ◽  
Spin Crossover ◽  
Molecular System ◽  
Uniaxial Strain ◽  
Strain Effect

Synergistic electrical bistability in a conductive spin crossover heterostructure

2015 ◽  
Vol 3 (5) ◽  
pp. 945-949 ◽  
Author(s):  
Yan-Cong Chen ◽  
Yan Meng ◽  
Zhao-Ping Ni ◽  
Ming-Liang Tong
Keyword(s):  
Electrical Conductivity ◽  
Spin Crossover ◽  
Electrical Bistability ◽  
Metallic Conductor

A flexible heterostructure is reported herein, which elastically couples the volumetric variation during SCO to the electrical conductivity of a strain-sensitive metallic conductor, thereby resulting in synergistic electrical bistability.

Electrical conductivity and spin crossover: Towards the first achievement with a metal bis dithiolene complex

2006 ◽  
Vol 142 (3-4) ◽  
pp. 261-266 ◽  
Author(s):  
Christophe Faulmann ◽  
Stéphane Dorbes ◽  
José A. Real ◽  
Lydie Valade
Keyword(s):  
Electrical Conductivity ◽  
Spin Crossover

Electrical Conductivity and Spin Crossover: Towards the First Achievement With a Metal Bis Dithiolene Complex

2007 ◽  
Vol 142 (3-4) ◽  
pp. 265-270 ◽  
Author(s):  
Christophe Faulmann ◽  
Stéphane Dorbes ◽  
José A. Real ◽  
Lydie Valade
Keyword(s):  
Electrical Conductivity ◽  
Spin Crossover

scholarly journals Anomalous Pressure Effects on the Electrical Conductivity of the Spin Crossover Complex [Fe(pyrazine){Au(CN)2}2]

2020 ◽  
Vol 6 (3) ◽  
pp. 31
Author(s):  
Andrei-Cristian Gheorghe ◽  
Yurii S. Bibik ◽  
Olesia I. Kucheriv ◽  
Diana D. Barakhtii ◽  
Marin-Vlad Boicu ◽  
...  
Keyword(s):  
Electrical Conductivity ◽  
Spin State ◽  
Spin Crossover ◽  
Activation Parameters ◽  
High Spin State ◽  
State Dependence ◽  
External Pressure ◽  
Pressure Effects ◽  
Nanocrystalline Powder ◽  
Crossover Point

We studied the spin-state dependence of the electrical conductivity of two nanocrystalline powder samples of the spin crossover complex [Fe(pyrazine){Au(CN)2}2]. By applying an external pressure (up to 3 kbar), we were able to tune the charge transport properties of the material from a more conductive low spin state to a crossover point toward a more conductive high spin state. We rationalize these results by taking into account the spin-state dependence of the activation parameters of the conductivity.

scholarly journals Spin state dependence of electrical conductivity of spin crossover materials

2012 ◽  
Vol 48 (35) ◽  
pp. 4163-4165 ◽  
Author(s):  
Aurelian Rotaru ◽  
Il'ya A. Gural'skiy ◽  
Gábor Molnár ◽  
Lionel Salmon ◽  
Philippe Demont ◽  
...  
Keyword(s):  
Electrical Conductivity ◽  
Spin State ◽  
Spin Crossover ◽  
State Dependence

scholarly journals New Spin-Crossover Compounds Containing the [Ni(mnt)] Anion (mnt = Maleonitriledithiolate)

2021 ◽  
Vol 7 (5) ◽  
pp. 72
Author(s):  
Scott S. Turner ◽  
Joanna Daniell ◽  
Hiroki Akutsu ◽  
Peter N. Horton ◽  
Simon J. Coles ◽  
...  
Keyword(s):  
Electrical Conductivity ◽  
Single Crystal ◽  
Spin Crossover ◽  
Variable Temperature ◽  
X Ray Diffraction ◽  
X Ray ◽  
Counter Ions ◽  
Bulk Magnetization ◽  
L1 And L2 ◽  
Derivatives Of

Two novel salts containing the anion [Ni(mnt)2]− (mnt = maleonitriledithiolate) have been synthesized. The counter-ions, [Fe(II)(L1 or L2)2], are cationic complexes where L1 and L2 are methylated derivatives of 2,6-bis(pyazolyl)pyridine or pyrazine, which are similar to ligands found in a series of spin-crossover (SCO) complexes. Both salts are characterized by variable temperature single crystal X-ray diffraction and bulk magnetization measurements. Compound 1, [Fe(II)(L1)2][Ni(mnt)2]2 displays an incomplete and gradual SCO up to 300 K, followed by a more rapid increase in the high-spin fraction between 300 and 350 K. Compound 2, [Fe(II)(L2)2][Ni(mnt)2]2.MeNO2, shows a gradual, but more complete SCO response centered at 250 K. For compound 2, the SCO is confirmed by variable temperature Mössbauer spectroscopy. In both cases, the anionic moieties are isolated from each other and so no electrical conductivity is observed.

Removing Substrate Background in TEM Microanalysis

1974 ◽  
Vol 32 ◽  
pp. 568-569
Author(s):  
John C. Russ ◽  
Nicholas C. Barbi
Keyword(s):  
Electrical Conductivity ◽  
Rapid Growth ◽  
Organic Film ◽  
Absolute Concentration ◽  
Background Signal ◽  
X Ray ◽  
Elemental Concentrations ◽  
Transmission Electron ◽  
Electron Microscopes ◽  
The Continuum

The rapid growth of interest in attaching energy-dispersive x-ray analysis systems to transmission electron microscopes has centered largely on microanalysis of biological specimens. These are frequently either embedded in plastic or supported by an organic film, which is of great importance as regards stability under the beam since it provides thermal and electrical conductivity from the specimen to the grid.Unfortunately, the supporting medium also produces continuum x-radiation or Bremsstrahlung, which is added to the x-ray spectrum from the sample. It is not difficult to separate the characteristic peaks from the elements in the specimen from the total continuum background, but sometimes it is also necessary to separate the continuum due to the sample from that due to the support. For instance, it is possible to compute relative elemental concentrations in the sample, without standards, based on the relative net characteristic elemental intensities without regard to background; but to calculate absolute concentration, it is necessary to use the background signal itself as a measure of the total excited specimen mass.

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