A New Series of Three-Dimensional Metal−Organic Framework, [M2(H2O)][C5N1H3(COO)2]3·2H2O, M = La, Pr, and Nd:  Synthesis, Structure, and Properties

2007 ◽  
Vol 46 (4) ◽  
pp. 1250-1258 ◽  
Author(s):  
Partha Mahata ◽  
Srinivasan Natarajan
Keyword(s):  
Metal Organic Framework ◽  
Three Dimensional ◽  
Structure And Properties ◽  
Metal Organic ◽  
Organic Framework

Synthesis, Structure, and Properties of a Chiral Zinc(II) Metal-Organic Framework Featuring Linear Trinuclear Secondary Building Blocks

2012 ◽  
Vol 65 (12) ◽  
pp. 1662 ◽  
Author(s):  
Zilu Chen ◽  
Chuanbing Zhang ◽  
Xianlin Liu ◽  
Zhong Zhang ◽  
Fupei Liang
Keyword(s):  
Building Block ◽  
Metal Organic Framework ◽  
Three Dimensional ◽  
Building Blocks ◽  
Triangular Prism ◽  
Structure And Properties ◽  
Adsorption Selectivity ◽  
One Dimensional ◽  
Metal Organic ◽  
Organic Framework

A chiral metal-organic framework formulated as [Zn3(L-TMTA)2(4,4′-bpy)4]·24H2O (1) was prepared from the reaction of Zn(NO3)2·6H2O with trimesoyltri(L-alanine) (L-TMTAH3) in the presence of 4,4′-bipyridine (4,4′-bpy). Compound 1 features linear trinuclear secondary building blocks [Zn3(syn-syn-COO)2(μ2,η3-COO)2]2+. Each linear trinuclear secondary building block is further linked to another eight ones around it by four L-TMTA3– ligands and eight 4,4′-bpy ligands, leading to the construction of a uninodal three-dimensional framework with triangular prism-like one-dimensional channels. Dehydrated compound 1 displays remarkable adsorption selectivity on CO2 and water vapour over N2 gas.

Synthesis, structure and properties of a new three-dimensional interpenetrated metal–organic framework with 3,3′-azodibenzoic acid (H2azdc) and 1,4-bis(1H-imidazol-1-yl)butane (bimb): {[Cd(azdc)(bimb)2]·H2O}n

2015 ◽  
Vol 71 (6) ◽  
pp. 485-490
Author(s):  
Ya-Qiang Zhong ◽  
Si-Chun Chen ◽  
Lei Zhang ◽  
Chu-Yue Jing ◽  
Kou-Lin Zhang
Keyword(s):  
Metal Organic Framework ◽  
Mixed Solvents ◽  
Three Dimensional ◽  
Structure And Properties ◽  
Coordination Environment ◽  
Carboxylate Groups ◽  
Metal Organic ◽  
Solution Reaction ◽  
Typical Solution ◽  
Organic Framework

A new three-dimensional interpenetrated CdII–organic framework based on 3,3′-azodibenzoic acid [3,3′-(diazenediyl)dibenzoic acid, H2azdc] and the auxiliary flexible ligand 1,4-bis(1H-imidazol-1-yl)butane (bimb), namely poly[[bis[μ2-1,4-bis(1H-imidazol-1-yl)butane-κ2N3:N3′][μ2-3,3′-(diazenediyl)dibenzoato-κ2O:O′]cadmium(II)] monohydrate], {[Cd(C14H8N2O4)(C10H14N2)2]·H2O}n, (1), was obtained by a typical solution reaction in mixed solvents (water andN,N′-dimethylformamide). Each CdIIcentre is six-coordinated by two O atoms of bis-monodentate bridging carboxylate groups from two azdc2−ligands and by four N atoms from four bimb ligands, forming an octahedral coordination environment. The CdIIions are connected by the bimb ligands, resulting in two-dimensional (4,4) layers, which are further pillared by the azdc2−ligands, affording a threefold interpenetrated three-dimensional α-Po topological framework with the Schläfli symbol 41263. The thermal stability and solid-state fluorescence properties of (1) have been investigated.

Three-dimensional hierarchical C-Co-N/Se derived from metal-organic framework as superior cathode for Li-Se batteries

2017 ◽  
Vol 363 ◽  
pp. 103-109 ◽  
Author(s):  
Jiarui He ◽  
Weiqiang Lv ◽  
Yuanfu Chen ◽  
Jie Xiong ◽  
Kechun Wen ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Three Dimensional ◽  
Metal Organic ◽  
Organic Framework

Electron transitions in a Ce(iii)-catecholate metal–organic framework

2022 ◽  
Author(s):  
Julia G. Knapp ◽  
Debmalya Ray ◽  
Paul B. Calio ◽  
Megan C. Wasson ◽  
Thais R. Scott ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Three Dimensional ◽  
Electron Transitions ◽  
Metal Organic ◽  
Organic Framework

Competitive electron transitions are present in a rare three-dimensional Ce(iii)-catecholate metal–organic framework.

Li-based MOF-derived multifunctional PEO polymer solid-state electrolyte for lithium energy storage

2022 ◽  
Author(s):  
Xiang Han ◽  
Tiantian Wu ◽  
Lanhui Gu ◽  
Dian Tian
Keyword(s):  
Energy Storage ◽  
Solid State ◽  
Metal Organic Framework ◽  
Three Dimensional ◽  
Isophthalic Acid ◽  
Solid State Electrolyte ◽  
Metal Organic ◽  
Solvothermal Conditions ◽  
Organic Framework

A three-dimensional (3D) metal-organic framework containing Li-oxygen clusters, namely {[Li2(IPA)]·DMF}n (1) (H2IPA = isophthalic acid), has been constructed under solvothermal conditions. The Li-based MOF can be applied to lithium energy...

Three-Dimensional Hierarchical Architectures Derived from Surface-Mounted Metal-Organic Framework Membranes for Enhanced Electrocatalysis

2017 ◽  
Vol 129 (44) ◽  
pp. 13969-13973 ◽  
Author(s):  
Gan Jia ◽  
Wen Zhang ◽  
Guozheng Fan ◽  
Zhaosheng Li ◽  
Degang Fu ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Three Dimensional ◽  
Metal Organic ◽  
Hierarchical Architectures ◽  
Organic Framework

A Novel (3,4,9)-Connected 3D Metal–Organic Framework Based on the Non-Planar Tricarboxyl Tecton and Zn5O4-Cluster SBU

2015 ◽  
Vol 68 (1) ◽  
pp. 161 ◽  
Author(s):  
Zhuo-Wei Wang ◽  
Hui Zhao ◽  
Min Chen ◽  
Min Hu
Keyword(s):  
Thermal Stability ◽  
Benzoic Acid ◽  
Metal Organic Framework ◽  
Three Dimensional ◽  
Crystalline Material ◽  
Tripodal Ligand ◽  
Secondary Building Units ◽  
Metal Organic ◽  
Organic Framework

Combination of a non-planar tripodal ligand 3,4-bi(4-carboxyphenyl)-benzoic acid (H3L) and Zn5O4-cluster secondary building units affords a highly connected three-dimensional metal–organic framework, {[Zn5(μ3-OH)3(μ2-OH)L2(H2O)2](H2O)2}n (1), which exhibits an unusual (3,4,9)-connected (42.5)(3.43.52)(32.45.511.613.73.82) topological net. The thermal stability and solid luminescence of the crystalline material have also been investigated.

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