scholarly journals Chemistry Surrounding Monomeric Copper(I) Methyl, Phenyl, Anilido, Ethoxide, and Phenoxide Complexes Supported byN-Heterocyclic Carbene Ligands:  Reactivity Consistent with Both Early and Late Transition Metal Systems

2006 ◽  
Vol 45 (22) ◽  
pp. 9032-9045 ◽  
Author(s):  
Laurel A. Goj ◽  
Elizabeth D. Blue ◽  
Samuel A. Delp ◽  
T. Brent Gunnoe ◽  
Thomas R. Cundari ◽  
...  
Keyword(s):  
Transition Metal ◽  
Late Transition Metal ◽  
Carbene Ligands ◽  
Late Transition ◽  
Methyl Phenyl

Optimizing bidentate N-heterocyclic carbene ligands for the modification of late transition metal surfaces – new insights through theory

2019 ◽  
Vol 21 (45) ◽  
pp. 24926-24934
Author(s):  
Melanie C. Börner ◽  
Johannes Neugebauer
Keyword(s):  
Transition Metal ◽  
Noble Metal ◽  
Metal Surfaces ◽  
Late Transition Metal ◽  
Adsorption Behaviour ◽  
Key Factors ◽  
Carbene Ligands ◽  
Transition Metal Surfaces ◽  
Late Transition

We identify key factors determining the adsorption behaviour of bidentate NHCs on noble metal surfaces.

Hydrosilylation as an efficient tool for polymer synthesis and modification with methacrylates

RSC Advances ◽  
2015 ◽  
Vol 5 (8) ◽  
pp. 5879-5885 ◽  
Author(s):  
Nuttapol Risangud ◽  
Zhijian Li ◽  
Athina Anastasaki ◽  
Paul Wilson ◽  
Kristian Kempe ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Polymer Synthesis ◽  
Late Transition Metal ◽  
Efficient Tool ◽  
Silicon Compounds ◽  
Late Transition

Hydrosilylation is a well-established reaction for the preparation of organo-silicon compounds, in which vinyl groups react with silanes (Si–H) usually catalysed by late transition metal complexes, most often Pt(ii) complexes.

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