Reduction of the Host Cationic Framework Charge by Isoelectronic Substitution:  Synthesis and Structure of Hg7Ag2P8X6(X = Br, I) and Hg6Ag4P8Br6

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Jarugu Narasimha Moorthy

Postsynthetic metal-node metathesis of a flexible, yet robust porous anionic Cd–MOF with different metal ions of varying ionic radii, charges and chemical nature leads to diverse isostructural MOFs. The Eu@MOF and Tb@MOF – accessed by PSME – are brilliantly luminescent. The modified MOFs permit organic dye separation.


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