Terpyridine Zn(II), Ru(III), and Ir(III) Complexes:  The Relevant Role of the Nature of the Metal Ion and of the Ancillary Ligands on the Second-Order Nonlinear Response of Terpyridines Carrying Electron Donor or Electron Acceptor Groups

Francesca Tessore; Dominique Roberto; Renato Ugo; Maddalena Pizzotti; Silvio Quici; Marco Cavazzini; Silvia Bruni; Filippo De Angelis

doi:10.1021/ic050975q

Terpyridine Zn(II), Ru(III), and Ir(III) Complexes: The Relevant Role of the Nature of the Metal Ion and of the Ancillary Ligands on the Second-Order Nonlinear Response of Terpyridines Carrying Electron Donor or Electron Acceptor Groups

Inorganic Chemistry ◽

10.1021/ic050975q ◽

2005 ◽

Vol 44 (24) ◽

pp. 8967-8978 ◽

Cited By ~ 70

Author(s):

Francesca Tessore ◽

Dominique Roberto ◽

Renato Ugo ◽

Maddalena Pizzotti ◽

Silvio Quici ◽

...

Keyword(s):

Electron Donor ◽

Electron Acceptor ◽

Metal Ion ◽

Nonlinear Response ◽

Second Order ◽

Ancillary Ligands ◽

Relevant Role

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Preponderant role of pentafluorophenyl moieties for tuning the electronic properties of extended benzodifuran-azomethine derivatives

New Journal of Chemistry ◽

10.1039/d1nj01132d ◽

2021 ◽

Author(s):

Chady Moussallem ◽

Magali Allain ◽

Frédéric Gohier ◽

Pierre Frere

Keyword(s):

Electronic Properties ◽

Electron Donor ◽

Electron Acceptor

From a central 3,7-bis(perfluorophenyl)-BDF unit, the extension performed with electron acceptor perfluorophenyl groups and/or electron donor N,N-dimethylamino groups via an imine link leads to symmetrical AAA and DAD or dissymmetrical...

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Synthesis and properties of a new second-order NLO chromophore containing the benzo[b]furan moiety for electro-optical materials

RSC Advances ◽

10.1039/c4ra04466e ◽

2014 ◽

Vol 4 (63) ◽

pp. 33312-33318 ◽

Cited By ~ 11

Author(s):

Maolin Zhang ◽

Guowei Deng ◽

Airui Zhang ◽

Huajun Xu ◽

Heyan Huang ◽

...

Keyword(s):

Electron Donor ◽

Optical Materials ◽

Furan Ring ◽

Second Order ◽

Donor Group ◽

Nlo Chromophores ◽

Furan Moiety

We have designed and synthesized a new chromophore having a 1,1,7,7-tetramethyljulolidine fused furan ring as the electron donor group to systematically investigate the role of the benzo[b]furan ring in NLO chromophores.

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Phosphole–Thiophene Hybrid: A Dual Role of Dithieno[3,4-b:3′,4′-d]phosphole as Electron Acceptor and Electron Donor

The Journal of Organic Chemistry ◽

10.1021/acs.joc.8b00030 ◽

2018 ◽

Vol 83 (6) ◽

pp. 3397-3402 ◽

Cited By ~ 4

Author(s):

Tomohiro Higashino ◽

Keiichi Ishida ◽

Takaharu Satoh ◽

Yoshihiro Matano ◽

Hiroshi Imahori

Keyword(s):

Electron Donor ◽

Electron Acceptor ◽

Dual Role

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High second-order nonlinear response of platinum nanoflowers: the role of surface corrugation

Nanoscale ◽

10.1039/c5nr07571h ◽

2016 ◽

Vol 8 (6) ◽

pp. 3489-3495 ◽

Cited By ~ 5

Author(s):

Hoang Minh Ngo ◽

Ngoc Diep Lai ◽

Isabelle Ledoux-Rak

Keyword(s):

Light Scattering ◽

Nonlinear Response ◽

Second Order ◽

Surface Corrugation ◽

Different Diameters ◽

First Time

We report the Harmonic Light scattering properties of PtNFs for six different diameters (∼7.0; 8.0; 10.0; 14.0; 20.0 and 31.0 nm). For the first time, very large β values of PtNFs are presented.

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New [(D-terpyridine)-Ru-(D or A-terpyridine)][4-EtPhCO2]2 complexes (D = electron donor group; A = electron acceptor group) as active second-order non linear optical chromophores

Dalton Transactions ◽

10.1039/c2dt30183k ◽

2012 ◽

Vol 41 (22) ◽

pp. 6707 ◽

Cited By ~ 15

Author(s):

Alessia Colombo ◽

Danika Locatelli ◽

Dominique Roberto ◽

Francesca Tessore ◽

Renato Ugo ◽

...

Keyword(s):

Electron Donor ◽

Electron Acceptor ◽

Second Order ◽

Donor Group ◽

Acceptor Group ◽

Non Linear ◽

Group A ◽

Linear Optical ◽

Optical Chromophores

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An Investigation on the Role of the Nature of Sulfonate Ancillary Ligands on the Strength and Concentration Dependence of the Second-Order NLO Responses in CHCl3of Zn(II) Complexes with 4,4‘-trans-NC5H4CHCHC6H4NMe2and 4,4‘-trans,trans-NC5H4(CHCH)2C6H4NMe2

Inorganic Chemistry ◽

10.1021/ic0487124 ◽

2005 ◽

Vol 44 (7) ◽

pp. 2437-2442 ◽

Cited By ~ 11

Author(s):

Francesca Tessore ◽

Danika Locatelli ◽

Stefania Righetto ◽

Dominique Roberto ◽

Renato Ugo ◽

...

Keyword(s):

Concentration Dependence ◽

Second Order ◽

Ancillary Ligands

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An EFISH, Theoretical, and PGSE NMR Investigation on the Relevant Role of Aggregation on the Second Order Response in CHCl3 of the Push−Pull Chromophores [5-[[4′-(Dimethylamino)phenyl]ethynyl]-15-[(4′′-nitrophenyl)ethynyl]-10,20-diphenylporphyrinate] M(II) (M = Zn, Ni)

The Journal of Physical Chemistry C ◽

10.1021/jp901919u ◽

2009 ◽

Vol 113 (25) ◽

pp. 11131-11141 ◽

Cited By ~ 15

Author(s):

Maddalena Pizzotti ◽

Francesca Tessore ◽

Alessio Orbelli Biroli ◽

Renato Ugo ◽

Filippo De Angelis ◽

...

Keyword(s):

Second Order ◽

Relevant Role ◽

Pgse Nmr

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Second-order classical nonlinear response theory

AIAA Journal ◽

10.2514/3.14824 ◽

2001 ◽

Vol 39 ◽

pp. 962-965

Author(s):

Abdulmuhsen H. Ali

Keyword(s):

Nonlinear Response ◽

Second Order ◽

Response Theory

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Differentiation of nucleotide binding sites and role of metal ion in the adenylate kinase reaction by 31P NMR. Equilibria, interconversion rates, and NMR parameters of bound substrates

Journal of Biological Chemistry ◽

10.1016/s0021-9258(17)38123-1 ◽

1978 ◽

Vol 253 (4) ◽

pp. 1149-1158 ◽

Cited By ~ 3

Author(s):

B.D. Nageswara Rao ◽

M. Cohn ◽

L. Noda

Keyword(s):

Binding Sites ◽

Adenylate Kinase ◽

Metal Ion ◽

31P Nmr ◽

Nucleotide Binding ◽

Nucleotide Binding Sites ◽

Nmr Parameters ◽

Kinase Reaction

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The Role of Extracellular Vesicles as Shuttles of RNA and Their Clinical Significance as Biomarkers in Hepatocellular Carcinoma

Genes ◽

10.3390/genes12060902 ◽

2021 ◽

Vol 12 (6) ◽

pp. 902

Author(s):

Eva Costanzi ◽

Carolina Simioni ◽

Gabriele Varano ◽

Cinzia Brenna ◽

Ilaria Conti ◽

...

Keyword(s):

Hepatocellular Carcinoma ◽

Extracellular Vesicles ◽

Tumor Metastasis ◽

Biological Processes ◽

Rna Molecules ◽

Expression Of Genes ◽

Non Coding Rna ◽

Donor Cells ◽

Relevant Role

Extracellular vesicles (EVs) have attracted interest as mediators of intercellular communication following the discovery that EVs contain RNA molecules, including non-coding RNA (ncRNA). Growing evidence for the enrichment of peculiar RNA species in specific EV subtypes has been demonstrated. ncRNAs, transferred from donor cells to recipient cells, confer to EVs the feature to regulate the expression of genes involved in differentiation, proliferation, apoptosis, and other biological processes. These multiple actions require accuracy in the isolation of RNA content from EVs and the methodologies used play a relevant role. In liver, EVs play a crucial role in regulating cell–cell communications and several pathophysiological events in the heterogeneous liver class of cells via horizontal transfer of their cargo. This review aims to discuss the rising role of EVs and their ncRNAs content in regulating specific aspects of hepatocellular carcinoma development, including tumorigenesis, angiogenesis, and tumor metastasis. We analyze the progress in EV-ncRNAs’ potential clinical applications as important diagnostic and prognostic biomarkers for liver conditions.

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