Two Novel Nanoporous Supramolecular Architectures Based on Copper(I) Coordination Polymers with Uniform (8, 3) and (8210) Nets:  In Situ Formation of Tetrazolate Ligands

2005 ◽  
Vol 44 (12) ◽  
pp. 4130-4132 ◽  
Author(s):  
Tao Wu ◽  
Bi-Hua Yi ◽  
Dan Li
2019 ◽  
Vol 10 (1) ◽  
Author(s):  
Anton Vladyka ◽  
Mickael L. Perrin ◽  
Jan Overbeck ◽  
Rubén R. Ferradás ◽  
Víctor García-Suárez ◽  
...  

2011 ◽  
Vol 47 (20) ◽  
pp. 5900 ◽  
Author(s):  
Dong-Hua Li ◽  
Jiang-Shan Shen ◽  
Na Chen ◽  
Yi-Bin Ruan ◽  
Yun-Bao Jiang

Crystals ◽  
2020 ◽  
Vol 10 (10) ◽  
pp. 893 ◽  
Author(s):  
Irina A. Kühne ◽  
Anthony B. Carter ◽  
George E. Kostakis ◽  
Christopher E. Anson ◽  
Annie K. Powell

This work reports the synthesis and structure of a large porous zeotype network observed within compound (1) using {Cu2(piv)4} as the linking unit (piv = pivalate). The slow in situ formation of the hmt ligand (hexamethylenetetramine) appears to be key in generating a µ4-bridging mode of the hmt-node. Attempts to improve the low yield of compound (1) using different solvent layer diffusion methods resulted in the µ3-hmt complexes (2) and (3). Both compounds exhibit a 3D network of two intertwined chiral networks. Strong hydrogen bonding present in (3) leads to the formation of intertwined, DNA-like double-helix structures. The use of bulky solvents in the synthesis of compound (4) leads to the structure crystallizing solvent-free. The packing of (4) is dominated by energy minimization, which is achieved when the 1D-“cylinders” pack into the closest possible arrangement. This work highlights the potential for solvent controlled synthesis of extended copper-hmt systems.


2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Anton Vladyka ◽  
Mickael L. Perrin ◽  
Jan Overbeck ◽  
Rubén R. Ferradás ◽  
Víctor García-Suárez ◽  
...  

CrystEngComm ◽  
2009 ◽  
Vol 11 (11) ◽  
pp. 2494 ◽  
Author(s):  
Zhen-Guo Zhao ◽  
Rong-Min Yu ◽  
Xiao-Yuan Wu ◽  
Qi-Sheng Zhang ◽  
Yi-Ming Xie ◽  
...  

2019 ◽  
Vol 491 (4) ◽  
pp. 5595-5620 ◽  
Author(s):  
Sanson T S Poon ◽  
Richard P Nelson ◽  
Seth A Jacobson ◽  
Alessandro Morbidelli

ABSTRACT The NASA’s Kepler mission discovered ∼700 planets in multiplanet systems containing three or more transiting bodies, many of which are super-Earths and mini-Neptunes in compact configurations. Using N-body simulations, we examine the in situ, final stage assembly of multiplanet systems via the collisional accretion of protoplanets. Our initial conditions are constructed using a subset of the Kepler five-planet systems as templates. Two different prescriptions for treating planetary collisions are adopted. The simulations address numerous questions: Do the results depend on the accretion prescription?; do the resulting systems resemble the Kepler systems, and do they reproduce the observed distribution of planetary multiplicities when synthetically observed?; do collisions lead to significant modification of protoplanet compositions, or to stripping of gaseous envelopes?; do the eccentricity distributions agree with those inferred for the Kepler planets? We find that the accretion prescription is unimportant in determining the outcomes. The final planetary systems look broadly similar to the Kepler templates adopted, but the observed distributions of planetary multiplicities or eccentricities are not reproduced, because scattering does not excite the systems sufficiently. In addition, we find that ∼1 per cent of our final systems contain a co-orbital planet pair in horseshoe or tadpole orbits. Post-processing the collision outcomes suggests that they would not significantly change the ice fractions of initially ice-rich protoplanets, but significant stripping of gaseous envelopes appears likely. Hence, it may be difficult to reconcile the observation that many low-mass Kepler planets have H/He envelopes with an in situ formation scenario that involves giant impacts after dispersal of the gas disc.


AIP Advances ◽  
2021 ◽  
Vol 11 (6) ◽  
pp. 065015
Author(s):  
Fu Yi ◽  
Xupeng Qi ◽  
Xuexin Zheng ◽  
Huize Yu ◽  
Wenming Bai ◽  
...  

2021 ◽  
Vol 202 ◽  
pp. 109535
Author(s):  
Yadong Wu ◽  
Xiuyan Cheng ◽  
Shaoyun Chen ◽  
Bo Qu ◽  
Rui Wang ◽  
...  

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