Puckered-Boat Conformation Hexameric Water Clusters Stabilized in a 2D Metal−Organic Framework Structure Built from Cu(II) and 1,2,4,5-Benzenetetracarboxylic Acid

2004 ◽  
Vol 43 (17) ◽  
pp. 5180-5182 ◽  
Author(s):  
Sujit K. Ghosh ◽  
Parimal K. Bharadwaj
Keyword(s):  
Water Clusters ◽  
Metal Organic Framework ◽  
Boat Conformation ◽  
Framework Structure ◽  
Metal Organic ◽  
Organic Framework

Enantiopure vs. racemic metalloligands: impact on metal–organic framework structure and synthesis

2007 ◽  
pp. 4881 ◽  
Author(s):  
Sergio J. Garibay ◽  
Jay R. Stork ◽  
Zhenqiang Wang ◽  
Seth M. Cohen ◽  
Shane G. Telfer
Keyword(s):  
Metal Organic Framework ◽  
Framework Structure ◽  
Metal Organic ◽  
Organic Framework

scholarly journals Facile isolation of a stable S6-symmetric methanol hexamer using the guest-free microporous metal-organic framework: zinc 5-tert-butyl isophthalate

2018 ◽  
Vol 233 (6) ◽  
pp. 429-435
Author(s):  
Samaila A. Jovial ◽  
James Raftery ◽  
Michael W. Anderson ◽  
Martin P. Attfield
Keyword(s):  
Metal Organic Framework ◽  
Structural Effect ◽  
Molecular Clusters ◽  
Ordered Structure ◽  
Framework Structure ◽  
Void Space ◽  
Tert Butyl ◽  
Metal Organic ◽  
Organic Framework

Abstract The ordered structure of the guest-free microporous metal-organic framework zinc 5-tert-butyl isophthalate {Zn[(CH3)3CC6H3(CO2)2]} has been determined and shown to be easily loaded with methanol to form {Zn[(CH3)3CC6H3(CO2)2]}·CH3OH. The methanol forms a S6-symmetric hexamer within the pores of the material that is uniquely defined by the void space and exerts a subtle structural effect on the framework structure of the host. The work demonstrates the use of this type of metal-organic framework as a matrix to isolate unique molecular clusters in a facile manner.

A hydrophobic semiconducting metal–organic framework assembled from silver chalcogenide wires

2020 ◽  
Vol 56 (14) ◽  
pp. 2091-2094 ◽  
Author(s):  
Jia-Yin Wang ◽  
Wen-Hua Li ◽  
Zhong Wei ◽  
Chong Zhang ◽  
Ya-Hui Li ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Metal Organic Framework ◽  
Carboxylate Ligand ◽  
Framework Structure ◽  
Silver Chalcogenide ◽  
Rigid Framework ◽  
Metal Organic ◽  
First Time ◽  
Organic Framework

Silver chalcogenide wires are for the first time assembled into a rigid framework structure using a fluorinated carboxylate ligand, where electron transfer along Ag–S chains enables semi-conduction.

Plasmonic Semiconductor Nanoparticles in a Metal–Organic Framework Structure and Their in Situ Cation Exchange

2016 ◽  
Vol 28 (20) ◽  
pp. 7511-7518 ◽  
Author(s):  
Andreas Wolf ◽  
Lisa Diestel ◽  
Franziska Lübkemann ◽  
Torben Kodanek ◽  
Tarek Mohamed ◽  
...  
Keyword(s):  
Cation Exchange ◽  
Metal Organic Framework ◽  
Semiconductor Nanoparticles ◽  
Framework Structure ◽  
Metal Organic ◽  
Organic Framework
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