Supramolecular Copper Hydroxide Tennis Balls:  Self-Assembly, Structures, and Magnetic Properties of Octanuclear [Cu8L8(OH)4]4+Clusters (HL =N-(2-Pyridylmethyl)acetamide)

2004 ◽  
Vol 43 (22) ◽  
pp. 7075-7082 ◽  
Author(s):  
Arunendu Mondal ◽  
Yang Li ◽  
Masood A. Khan ◽  
Joseph H. Ross, ◽  
Robert P. Houser
Nanoscale ◽  
2021 ◽  
Vol 13 (8) ◽  
pp. 4519-4529
Author(s):  
J. Mohapatra ◽  
J. Elkins ◽  
M. Xing ◽  
D. Guragain ◽  
Sanjay R. Mishra ◽  
...  

Self-assembly of nanoparticles into ordered patterns is a novel approach to build up new consolidated materials with desired collective physical properties.


2015 ◽  
Vol 17 (41) ◽  
pp. 27653-27657 ◽  
Author(s):  
Jeffrey E. Chen ◽  
Hong-Yuan Lian ◽  
Saikat Dutta ◽  
Saad M. Alshehri ◽  
Yusuke Yamauchi ◽  
...  

This study illustrates the directed self-assembly of mesoporous TiO2 with magnetic properties due to its colloidal crystal structure with Fe3O4.


2002 ◽  
Vol 739 ◽  
Author(s):  
Benjamin L. Frankamp ◽  
Andrew K. Boal ◽  
Vincent M. Rotello

ABSTRACTControl of particle-particle spacing is a key determinant of optical, electronic, and magnetic properties of nanocomposite materials. We have used poly(amidoamine) (PAMAM) dendrimers to assemble carboxylic acid-functionalized mixed monolayer protected clusters (MMPCs) through acid/base chemistry between particle and polymer. IR spectroscopy and selective dendrimer staining, observed by Transmission Electron Microscopy (TEM), establish that the PAMAM dendrimers are the mortar in the assembly and act to space the MMPCs in the resulting aggregates. Small angle X-ray scattering (SAXS) was then used to establish average interparti cle distances; five generations of PAMAM dendrimer (0, 1, 2, 4, 6) were investigated and monotonic increase in interparticle spacing from 4.1 nm to 6.1 nm was observed.Initial studies involving the application of this methodology to control the magnetic properties of 3-iron oxide nanoparticles have been completed. γ-Iron oxide nanoparticles (6.5 nm in diameter) have been assembled with PAMAM dendrimers generations 2.5, 4.5, and 6.5. The resulting aggregates were characterized with SAXS and magnetization obtained on a super conducting quantum interference devise (SQUID). An observed correlation between the blocking temperature (TB) and the average interparticle spacing suggests that our methodology could be used to tailor the magnetic profile of the nanoparticles.


2021 ◽  
Vol 50 (1) ◽  
pp. 262-269
Author(s):  
Jianfeng Wu ◽  
Qianqian Yang ◽  
Haoyu Wang ◽  
Yan Ge ◽  
Jinkui Tang ◽  
...  

The anion-adaptive self-assembly described here not only offers a facile approach to produce large single-molecule magnets but also provides an understanding of how structural factors affect the magnetic properties.


2004 ◽  
Vol 16 (17) ◽  
pp. 3252-3256 ◽  
Author(s):  
Andrew K. Boal ◽  
Benjamin L. Frankamp ◽  
Oktay Uzun ◽  
Mark T. Tuominen ◽  
Vincent M. Rotello

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