Carbon−Halogen Bond Activation Mechanism by Copper(I) Complexes of (2-Pyridyl)alkylamine Ligands

2005 ◽  
Vol 44 (2) ◽  
pp. 410-415 ◽  
Author(s):  
Takao Osako ◽  
Kenneth D. Karlin ◽  
Shinobu Itoh
Keyword(s):  
Bond Activation ◽  
Halogen Bond ◽  
Activation Mechanism

Mechanistic insights into α-branched amines formation with pivalic acid assisted C−H bond activation catalysed by Cp*Rh complexes

2021 ◽  
Author(s):  
Rongrong Li ◽  
Xinzheng Yang
Keyword(s):  
Density Functional Theory ◽  
Density Functional ◽  
Bond Activation ◽  
Pivalic Acid ◽  
Activation Mechanism ◽  
Functional Theory ◽  
Density Functional Theory Computations ◽  
Reaction Energies

Density functional theory computations revealed a pivalic acid assisted C−H bond activation mechanism for rhodium catalyzed formation of α-branched amines with C−C and C−N bond couplings. The reaction energies of...

Dicationic oligotelluroxane or mononuclear telluronium cation? Elucidation of true catalytic species and activation mechanism of benzylic carbon-halogen bond

2021 ◽  
Author(s):  
Koji Takagi ◽  
Nao Sakakibara ◽  
Shoko Kikkawa ◽  
Seiji Tsuzuki
Keyword(s):  
Time Course ◽  
Halogen Bond ◽  
Activation Mechanism ◽  
Nmr Analysis ◽  
Benzylic Carbon

The application of diaryltelluronium cations as a chalcogen bonding organocatalyst was investigated for the Ritter-like reaction using the time-course NMR analysis. The resistance to water of dicationic oligotelluroxanes differed depending...

Silicon-Halogen Bond Activation in Mixed Si/Al Compounds and an Approach to Intramolecular Stabilized Silylium Ions

2019 ◽  
Vol 2019 (5) ◽  
pp. 693-711 ◽  
Author(s):  
Werner Uhl ◽  
Michael Tolzmann ◽  
Kira Willeke ◽  
Christian Honacker ◽  
Alexander Hepp ◽  
...  
Keyword(s):  
Bond Activation ◽  
Halogen Bond

Chelation-Assisted Carbon-Halogen Bond Activation by a Rhodium(I) Complex

2009 ◽  
Vol 48 (3) ◽  
pp. 1198-1206 ◽  
Author(s):  
Shanshan Chen ◽  
Yongxin Li ◽  
Jing Zhao ◽  
Xingwei Li
Keyword(s):  
Bond Activation ◽  
Halogen Bond

scholarly journals Carbon-Halogen Bond Activation by Selenium-Based Chalcogen Bonding

2017 ◽  
Vol 56 (39) ◽  
pp. 12009-12012 ◽  
Author(s):  
Patrick Wonner ◽  
Lukas Vogel ◽  
Maximilian Düser ◽  
Luís Gomes ◽  
Florian Kniep ◽  
...  
Keyword(s):  
Bond Activation ◽  
Halogen Bond

Theoretical studies on the N–X (X = Cl, O) bond activation mechanism in catalytic C–H amination

2020 ◽  
Vol 10 (6) ◽  
pp. 1914-1924
Author(s):  
Yang Yu ◽  
Gen Luo ◽  
Jimin Yang ◽  
Yi Luo
Keyword(s):  
Bond Activation ◽  
Bond Cleavage ◽  
Activation Mechanism ◽  
Theoretical Studies

A favorable SN2-type N–Cl bond cleavage mechanism are proposed for Rh-catalysed C–H amination, which also works for N–O bond cleavage in Rh, Ru, and Pd analogous systems. These results could provide new understanding of C–H amination.

ChemInform Abstract: Organocatalysis Through Halogen-Bond Activation.

ChemInform ◽  
2008 ◽  
Vol 39 (32) ◽  
Author(s):  
Angelika Bruckmann ◽  
Miguel A. Pena ◽  
Carsten Bolm
Keyword(s):  
Bond Activation ◽  
Halogen Bond

Aliphatic C–X (X=halogen) bond activation by transition metal complexes containing the {Pt2S2} core: A theoretical study of the reaction mechanism

2006 ◽  
Vol 359 (11) ◽  
pp. 3736-3744 ◽  
Author(s):  
Ainara Nova ◽  
Pilar González-Duarte ◽  
Agustı́ Lledós ◽  
Ruben Mas-Ballesté ◽  
Gregori Ujaque
Keyword(s):  
Reaction Mechanism ◽  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Bond Activation ◽  
Theoretical Study ◽  
Halogen Bond
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