scholarly journals Behavior of Tri(n-butyl)ammonium Bis[citrato(3−)-O1,O3,O6]silicate in Aqueous Solution:  Analysis of a Sol−Gel Process by Small-Angle Neutron Scattering

2005 ◽  
Vol 44 (7) ◽  
pp. 2318-2325 ◽  
Author(s):  
Oliver Seiler ◽  
Christian Burschka ◽  
Dietmar Schwahn ◽  
Reinhold Tacke
1989 ◽  
Vol 166 ◽  
Author(s):  
P. Wiltzius ◽  
S. B. Dierker

ABSTRACTWe present small angle neutron scattering data of porous glasses. Analysis of the structure factor shows that the morphology on length scales between 30 A and 800 A depends on fabrication procedures. Fast gelation leads to a clumpy glass, whereas slow gelation produces a random smooth internal interface.


2003 ◽  
Vol 36 (1) ◽  
pp. 1-6 ◽  
Author(s):  
Sara Romer ◽  
Claus Urban ◽  
Vladimir Lobaskin ◽  
Frank Scheffold ◽  
Anna Stradner ◽  
...  

A new sample environment has been developed in order to perform light and small-angle neutron scattering (SANS) simultaneously on colloidal systems. The combination of SANS and diffusing wave spectroscopy (DWS) is of particular use in the high-concentration regime. DWS provides information on the local dynamic properties of the individual particles, whereas SANS gives access to the structural properties on similar length scales. The combination of both methods thus allows one to obtain structural and dynamic information over a very large range of length and time scales. Using this new setup, the onset of aggregation and the sol–gel transition in concentrated destabilized polystyrene sphere suspensions have been investigated. At the gel point, a dramatic change of the particle dynamics from diffusion to a subdiffusive arrested motion is observed. However, while the DWS measurements indicate that dramatic changes in the local dynamics occur over a long period, the SANS pattern quickly reaches its final appearance. The SANS experiments thus indicate that a fluid-like structure is arrested in the course of the gel formation. The data are found to be in good qualitative agreement with computer simulations.


2001 ◽  
Vol 38 (12) ◽  
pp. 1175-1189 ◽  
Author(s):  
Deli Wang ◽  
Daniel Moses ◽  
Guillermo Bazan ◽  
Alan Heeger ◽  
Jyostana Lal

2020 ◽  
Vol 22 (22) ◽  
pp. 12524-12531
Author(s):  
Boyang Zhou ◽  
Alberto Fernandez-Nieves ◽  
Wei-Ren Chen ◽  
Tae-Hwan Kim ◽  
Changwoo Do

We investigate the phase behaviours of Pluronic L62 in aqueous solution in the presence of aerosol-OT (AOT) molecules by small angle neutron scattering (SANS).


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