New Lanthanide Complexes for Sensitized Visible and Near-IR Light Emission:  Synthesis,1H NMR, and X-ray Structural Investigation and Photophysical Properties

2004 ◽  
Vol 43 (4) ◽  
pp. 1294-1301 ◽  
Author(s):  
Silvio Quici ◽  
Giovanni Marzanni ◽  
Alessandra Forni ◽  
Gianluca Accorsi ◽  
Francesco Barigelletti
2021 ◽  
Vol 503 (1) ◽  
pp. 614-624
Author(s):  
F M Vincentelli ◽  
P Casella ◽  
D M Russell ◽  
M C Baglio ◽  
A Veledina ◽  
...  

ABSTRACT We present the results regarding the analysis of the fast X-ray/infrared (IR) variability of the black hole transient MAXI J1535−571. The data studied in this work consist of two strictly simultaneous observations performed with XMM–Newton (X-rays: 0.7–10 keV), VLT/HAWK-I (Ks band, 2.2 μm) and VLT/VISIR (M and PAH2_2 bands, 4.85 and 11.88 μm, respectively). The cross-correlation function between the X-ray and near-IR light curves shows a strong asymmetric anticorrelation dip at positive lags. We detect a near-IR QPO (2.5σ) at 2.07 ± 0.09 Hz simultaneously with an X-ray QPO at approximately the same frequency (f0 = 2.25 ± 0.05). From the cross-spectral analysis, a lag consistent with zero was measured between the two oscillations. We also measure a significant correlation between the average near-IR and mid-IR fluxes during the second night, but find no correlation on short time-scales. We discuss these results in terms of the two main scenarios for fast IR variability (hot inflow and jet powered by internal shocks). In both cases, our preliminary modelling suggests the presence of a misalignment between the disc and jet.


2019 ◽  
Vol 48 (25) ◽  
pp. 9365-9375 ◽  
Author(s):  
James N. McPherson ◽  
Laura Abad Galan ◽  
Hasti Iranmanesh ◽  
Massimiliano Massi ◽  
Stephen B. Colbran

Nine-coordinate tris(dipyridylpyrrolide)lanthanide(iii) complexes were readily obtained, and were investigated by X-ray crystallography, NMR spectroscopy, and photophysical and electrochemical studies.


Author(s):  
C. Jacobsen ◽  
J. Fu ◽  
S. Mayer ◽  
Y. Wang ◽  
S. Williams

In scanning luminescence x-ray microscopy (SLXM), a high resolution x-ray probe is used to excite visible light emission (see Figs. 1 and 2). The technique has been developed with a goal of localizing dye-tagged biochemically active sites and structures at 50 nm resolution in thick, hydrated biological specimens. Following our initial efforts, Moronne et al. have begun to develop probes based on biotinylated terbium; we report here our progress towards using microspheres for tagging.Our initial experiments with microspheres were based on commercially-available carboxyl latex spheres which emitted ~ 5 visible light photons per x-ray absorbed, and which showed good resistance to bleaching under x-ray irradiation. Other work (such as that by Guo et al.) has shown that such spheres can be used for a variety of specific labelling applications. Our first efforts have been aimed at labelling ƒ actin in Chinese hamster ovarian (CHO) cells. By using a detergent/fixative protocol to load spheres into cells with permeabilized membranes and preserved morphology, we have succeeded in using commercial dye-loaded, spreptavidin-coated 0.03μm polystyrene spheres linked to biotin phalloidon to label f actin (see Fig. 3).


2020 ◽  
Vol 24 (10) ◽  
pp. 1139-1147
Author(s):  
Yang Mingyan ◽  
Wang Daoquan ◽  
Wang Mingan

2-Phenylcyclododecanone and 2-cyclohexylcyclododecanone derivatives were synthesized and characterized by 1H NMR, 13C NMR, HR-ESI-MS and X-ray diffraction. Their preferred conformations were analyzed by the coupling constants in the 1H NMR spectra and X-ray diffraction, which showed the skeleton ring of these derivatives containing [3333]-2-one conformation, and the phenyl groups were located at the side-exo position of [3333]-2-one conformation due to the strong π-π repulsive interaction between the π- electron of benzene ring and π-electron of carbonyl group. The cyclohexyl groups were located at the corner-syn or the side-exo position of [3333]-2-one conformation depending on the hindrance of the other substituted groups. The π-π electron effect played a crucial role in efficiently controlling the preferred conformation of 2-aromatic cyclododecanone and the other 2-aromatic macrocyclic derivatives with the similar preferred square and rectangular conformations.


2020 ◽  
Vol 15 (S359) ◽  
pp. 17-21
Author(s):  
Karín Menéndez-Delmestre ◽  
Laurie Riguccini ◽  
Ezequiel Treister

AbstractThe coexistence of star formation and AGN activity has geared much attention to dusty galaxies at high redshifts, in the interest of understanding the origin of the Magorrian relation observed locally, where the mass of the stellar bulk in a galaxy appears to be tied to the mass of the underlying supermassive black hole. We exploit the combined use of far-infrared (IR) Herschel data and deep Chandra ˜160 ksec depth X-ray imaging of the COSMOS field to probe for AGN signatures in a large sample of >100 Dust-Obscured Galaxies (DOGs). Only a handful (˜20%) present individual X-ray detections pointing to the presence of significant AGN activity, while X-ray stacking analysis on the X-ray undetected DOGs points to a mix between AGN activity and star formation. Together, they are typically found on the main sequence of star-forming galaxies or below it, suggesting that they are either still undergoing significant build up of the stellar bulk or have started quenching. We find only ˜30% (6) Compton-thick AGN candidates (NH > 1024 cm–2), which is the same frequency found within other soft- and hard-X-ray selected AGN populations. This suggests that the large column densities responsible for the obscuration in Compton-thick AGNs must be nuclear and have little to do with the dust obscuration of the host galaxy. We find that DOGs identified to have an AGN share similar near-IR and mid-to-far-IR colors, independently of whether they are individually detected or not in the X-ray. The main difference between the X-ray detected and the X-ray undetected populations appears to be in their redshift distributions, with the X-ray undetected ones being typically found at larger distances. This strongly underlines the critical need for multiwavelength studies in order to obtain a more complete census of the obscured AGN population out to higher redshifts. For more details, we refer the reader to Riguccini et al. (2019).


2021 ◽  
Vol 2021 (9) ◽  
pp. 831-839
Author(s):  
Vanitha Ramu ◽  
Paramita Kundu ◽  
Aarti Upadhyay ◽  
Paturu Kondaiah ◽  
Akhil R. Chakravarty

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