Self-Assembly of Lanthanide Helicate Coordination Polymers into 3D Metal-Organic Framework Structures

2004 ◽  
Vol 43 (7) ◽  
pp. 2293-2298 ◽  
Author(s):  
Sujit K. Ghosh ◽  
Parimal K. Bharadwaj
Keyword(s):  
Coordination Polymers ◽  
Self Assembly ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Organic Framework

scholarly journals Millimeter-Scale Zn(3-ptz)2 Metal–Organic Framework Single Crystals: Self-Assembly Mechanism and Growth Kinetics

ACS Omega ◽  
2021 ◽  
Author(s):  
Juan M. Garcia-Garfido ◽  
Javier Enríquez ◽  
Ignacio Chi-Durán ◽  
Iván Jara ◽  
Leonardo Vivas ◽  
...  
Keyword(s):  
Single Crystals ◽  
Growth Kinetics ◽  
Self Assembly ◽  
Metal Organic Framework ◽  
Assembly Mechanism ◽  
Metal Organic ◽  
Organic Framework

scholarly journals Defect self-assembly of metal-organic framework triggers ferroptosis to overcome resistance

2021 ◽  
Author(s):  
Haibao Peng ◽  
Xingcai Zhang ◽  
Peng Yang ◽  
Jiaxu Zhao ◽  
Wei Zhang ◽  
...  
Keyword(s):  
Self Assembly ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Organic Framework

Encapsulation of [(SO4)4(H2O)12]8− clusters in a metal organic framework of pyridyl functionalized cyanuric acid based tris-urea

2015 ◽  
Vol 44 (34) ◽  
pp. 15075-15078 ◽  
Author(s):  
Ranjan Dutta ◽  
Bidyut Akhuli ◽  
Pradyut Ghosh
Keyword(s):  
Self Assembly ◽  
Cyanuric Acid ◽  
Metal Organic Framework ◽  
Hydrated Form ◽  
Metal Organic ◽  
Organic Framework

Encapsulation of four sulfates in hydrated form is demonstrated in the coordination driven self-assembly of a tripodal urea receptor.

scholarly journals Nanopore-induced host–guest charge transfer phenomena in a metal–organic framework

2018 ◽  
Vol 9 (13) ◽  
pp. 3282-3289 ◽  
Author(s):  
S. Yamamoto ◽  
J. Pirillo ◽  
Y. Hijikata ◽  
Z. Zhang ◽  
K. Awaga
Keyword(s):  
Charge Transfer ◽  
Self Assembly ◽  
Metal Organic Framework ◽  
Donor And Acceptor ◽  
Organic Electron ◽  
Donor Acceptor ◽  
Metal Organic ◽  
Bulk Scale ◽  
A Charge ◽  
Organic Framework

Using the “crystal sponge” approach, weak organic electron donor molecules were impregnated and evenly distributed in a crystal of a metal–organic framework (MOF), with the self-assembly of the donor–acceptor pairs with electron acceptor ligands. The nanopores of the MOF confined them and induced a charge transfer phenomenon, which would not occur between donor and acceptor molecules in a bulk scale.

Dye encapsulated zinc-based metal-organic framework as a dual-emission sensor for highly sensitive detection of antibiotics

2021 ◽  
Author(s):  
Kang Wang ◽  
Yuhan Duan ◽  
Jiajing Chen ◽  
Haiying Wang ◽  
Hui-Yan Liu
Keyword(s):  
Self Assembly ◽  
Metal Organic Framework ◽  
Sensitive Detection ◽  
Dual Emission ◽  
Highly Sensitive ◽  
Metal Organic ◽  
Highly Sensitive Detection ◽  
Organic Framework

Self-assembly of two Zn-MOFs, [Zn2L(DMF)3]•H2O•5DMF (1) and [Zn2L(H2O)2]•4H2O•3DMF (2) were achieved with an amide-functionalized tetracarboxylate ligand under similar conditions. Incorporated amide groups make the tetratopic linkers exhibit different configurations, tetrahedron...

scholarly journals Multi-Metals CaMgAl Metal-Organic Framework as CaO-based Sorbent to Achieve Highly CO2 Capture Capacity and Cyclic Performance

Materials ◽  
2020 ◽  
Vol 13 (10) ◽  
pp. 2220 ◽  
Author(s):  
Szu-Chen Wu ◽  
Po-Hsueh Chang ◽  
Chieh-Yen Lin ◽  
Cheng-Hsiung Peng
Keyword(s):  
Metal Ions ◽  
Co2 Capture ◽  
Self Assembly ◽  
Metal Organic Framework ◽  
Hydrothermal Process ◽  
Gravimetric Analysis ◽  
Metal Organic ◽  
Co2 Capture Capacity ◽  
Capture Capacity ◽  
Organic Framework

In this study, Ca-based multi-metals metal-organic framework (CaMgAl-MOF) has been designed as precursor material for carbon dioxide (CO2) capture to enhance the CO2 capture capacity and stability during multiple carbonation-calcination cycles. The CaMgAl-MOFs were constructed from self-assembly of metal ions and organic ligands through hydrothermal process to make metal ions uniformly distributed through the whole structure. Upon heat treatment at 600 °C, the Ca-based multi-metals CaMgAl-MOF would gradually transform to CaO and MgO nanoparticles along with the amorphous aluminum oxide distributed in the CaO matrix. XRD, Fourier transform infrared (FTIR), and SEM were used to identify the structure and characterize the morphology. The CO2 capture capacity and multiple carbonation-calcination cyclic tests of calcined Ca-based metal-organic framework (MOF) (attached with O and indicated as Ca-MOF-O) were performed by thermal gravimetric analysis (TGA). The single metal component calcined Ca-MOF sorbent have the highest CO2 capture capacity up to 72 wt.%, but a lower stability of 61% due to severe particle aggregation. In contrast, a higher Ca-rich MOF oxide sorbent with tailoring the Mg/Al ratios, Ca0.97Mg0.025Al0.005-MOF-O, showed the best performance, not only having the high stability of ~97%, but also maintaining the highest capacity of 71 wt.%. The concept of using Ca-based MOF materials combined with mixed-metal ions for CO2 capture showed a potential route for achieving efficient multiple carbonation-calcination CO2 cycles.

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