A New Family of Spin Crossover Complexes with a Tripod Ligand Containing Three Imidazoles:  Synthesis, Characterization, and Magnetic Properties of [FeIIH3LMe](NO3)2·1.5H2O, [FeIIILMe]·3.5H2O, [FeIIH3LMe][FeIILMe]NO3, and [FeIIH3LMe][FeIIILMe](NO3)2(H3LMe= Tris[2-(((2-methylimidazol-4-yl)methylidene)amino)ethyl]amine)

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Shutaro Osa ◽  
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Two isostructural iron(iii) spin crossover complexes show anion-size dependent spin crossover.


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New Hofmann-type metal–organic frameworks display rare and complete ligand exchange induced single crystal to single crystal transformations from 3D frameworks to 2D layers, accompanied by magnetic properties transition from two-step SCO behavior to hysteretic SCO behavior.


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