Encapsulation of Cobalt Phthalocyanine in Zeolite-Y: Evidence for Nonplanar Geometry

2003 ◽  
Vol 42 (5) ◽  
pp. 1711-1719 ◽  
Author(s):  
Saumi Ray ◽  
S. Vasudevan
Keyword(s):  
Zeolite Y ◽  
Cobalt Phthalocyanine ◽  
Nonplanar Geometry

Encapsulation of a Ni salen complex in zeolite Y: an experimental and DFT study

2015 ◽  
Vol 44 (8) ◽  
pp. 3753-3763 ◽  
Author(s):  
Archana Choudhary ◽  
Bidisa Das ◽  
Saumi Ray
Keyword(s):  
Magnetic Properties ◽  
Zeolite Y ◽  
Dft Study ◽  
Nonplanar Geometry ◽  
Salen Complex

A planar diamagnetic Ni-complex when encapsulated in zeolite Y adopts a nonplanar geometry and shows a pragmatic change in its magnetic properties.

Surface roughness measurements of vanadium-contaminated fluidized cracking catalysts by atomic force microscopy

1996 ◽  
Vol 54 ◽  
pp. 866-867
Author(s):  
H. Kinney ◽  
M.L. Occelli ◽  
S.A.C. Gould
Keyword(s):  
Surface Roughness ◽  
Zeolite Y ◽  
Atomic Level ◽  
Microporous Structure ◽  
Contact Mode ◽  
Force Microscopy ◽  
Atomic Force ◽  
Before And After ◽  
Roughness Measurements ◽  
Cracking Catalysts

For this study we have used a contact mode atomic force microscope (AFM) to study to topography of fluidized cracking catalysts (FCC), before and after contamination with 5% vanadium. We selected the AFM because of its ability to well characterize the surface roughness of materials down to the atomic level. It is believed that the cracking in the FCCs occurs mainly on the catalysts top 10-15 μm suggesting that the surface corrugation could play a key role in the FCCs microactivity properties. To test this hypothesis, we chose vanadium as a contaminate because this metal is capable of irreversibly destroying the FCC crystallinity as well as it microporous structure. In addition, we wanted to examine the extent to which steaming affects the vanadium contaminated FCC. Using the AFM, we measured the surface roughness of FCCs, before and after contamination and after steaming.We obtained our FCC (GRZ-1) from Davison. The FCC is generated so that it contains and estimated 35% rare earth exchaged zeolite Y, 50% kaolin and 15% binder.

SO3H-functionalized Zeolite-Y as an Efficient Nanocatalyst for the Synthesis of Nbenzimidazole- 2-aryl-4-thiazolidinones and tri-substituted Imidazoles

2020 ◽  
Vol 17 (2) ◽  
pp. 117-130 ◽  
Author(s):  
Mehdi Kalhor ◽  
Zohre Zarnegar ◽  
Zahra Seyedzade ◽  
Soodabeh Banibairami
Keyword(s):  
Zeolite Y ◽  
Internal Standard ◽  
Acid Catalyst ◽  
Aromatic Aldehydes ◽  
Reaction Rates ◽  
Ambient Conditions ◽  
Catalytic Method ◽  
Efficient Catalyst ◽  
Bet Analysis ◽  
Ft Ir

Background: SO3H-functionalized zeolite-Y was prepared and used as a catalyst for the synthesis of 2-aryl-N-benzimidazole-4-thiazolidinones and tri-substituted imidazoles at ambient conditions. Objective: The goals of this catalytic method include excellent yields and high purity, inexpensive procedure and ease of product isolation, the use of nontoxic and heterogeneous acid catalyst, shorter reaction times and milder conditions. Materials and Methods: NMR spectra were recorded on Brucker spectrophotometer using Me4Si as internal standard. Mass spectra were recorded on an Agilent Technology 5975C VL MSD with tripe-axis detector. FTIR spectra were obtained with KBr disc on a galaxy series FT-IR 5000 spectrometer. The surface morphology of nanostructures was analyzed by FE-SEM (EVO LS 10, Zeiss, Carl Zeiss, Germany). BET analysis were measured at 196 °C by a Japan Belsorb II system after the samples were vacuum dried at 150°C overnight. Results: The NSZ was characterized by FT-IR, FESEM, EDX, XRF, and BET. The catalytic activity of NSZ was investigated for synthesis of 1,3-tiazolidin-4-ones in H2O/Acetone at room temperature. Moreover, NSZ was used for synthesis of tri-substituted imidazoles at 60 °C via solvent-free condensation. Different kinds of aromatic aldehydes were converted to the corresponding of products with good to excellent yields. Conclusion: Sulfonated zeolite-Y was as an efficient catalyst for the preparation of N-benzimidazole-2-aryl-1,3- thiazolidin-4-ones and 2,4,5-triaryl-1H-imidazoles. High reaction rates, elimination toxic solvent, simple experimental procedure and reusability of the catalyst are the important features of this protocol.

Derivatization of SWCNTs with cobalt phthalocyanine residues and applications in screen printed electrodes for electrochemical detection of thiocholine

2011 ◽  
Vol 56 (11) ◽  
pp. 3988-3995 ◽  
Author(s):  
Elena Jubete ◽  
Kamila Żelechowska ◽  
Oscar A. Loaiza ◽  
Pedro J. Lamas ◽  
Estibalitz Ochoteco ◽  
...  
Keyword(s):  
Electrochemical Detection ◽  
Cobalt Phthalocyanine ◽  
Screen Printed Electrodes ◽  
Screen Printed

scholarly journals Berichtigung: Enhancing CO 2 Electroreduction to Methane with a Cobalt Phthalocyanine and Zinc–Nitrogen–Carbon Tandem Catalyst

2021 ◽  
Vol 133 (8) ◽  
pp. 3895-3895
Author(s):  
Long Lin ◽  
Tianfu Liu ◽  
Jianping Xiao ◽  
Hefei Li ◽  
Pengfei Wei ◽  
...  
Keyword(s):  
Cobalt Phthalocyanine

scholarly journals Quantification of Classified Nickel Species in Spent FFC Catalysts

2021 ◽  
Author(s):  
Monica Dapiaggi ◽  
Marco Alloni ◽  
Riccardo Carli ◽  
Nicola Rotiroti ◽  
Giorgia Confalonieri
Keyword(s):  
Zeolite Y ◽  
Complex Matrix ◽  
Spent Catalyst ◽  
Quick Method ◽  
Spent Catalysts ◽  
The Law ◽  
The One ◽  
Nickel Species

Abstract The paper presents a quick method for the quantification of nickel species in spent FFC catalysts; the quantification of known quantities NiO and $$\hbox{NiAl}_2\hbox{O}_{4}$$ NiAl 2 O 4 is first done in a matrix of fresh zeolite Y, and then in a complex matrix, similar to the one of a real spent catalyst. The method is carefully checked and the errors in the quantification are critically evaluated. After the validation of the method with known quantities of NiO, well below the law limit for direct re-use, a set of real spent catalysts (representative of a period of 12 months) is analysed. Graphic Abstract

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