Transition from Hydrogen Atom to Hydride Abstraction by Mn4O4(O2PPh2)6versus [Mn4O4(O2PPh2)6]+:  O−H Bond Dissociation Energies and the Formation of Mn4O3(OH)(O2PPh2)6

2003 ◽  
Vol 42 (9) ◽  
pp. 2849-2858 ◽  
Author(s):  
Thomas G. Carrell ◽  
Emilie Bourles ◽  
Matthew Lin ◽  
G. Charles Dismukes
Keyword(s):  
Hydrogen Atom ◽  
Bond Dissociation Energies ◽  
Bond Dissociation ◽  
Dissociation Energies ◽  
Hydride Abstraction

Hydrogen atom abstraction reactions independent of C–H bond dissociation energies of organic substrates in water: significance of oxidant–substrate adduct formation

2014 ◽  
Vol 5 (4) ◽  
pp. 1429-1436 ◽  
Author(s):  
Tomoya Ishizuka ◽  
Shingo Ohzu ◽  
Hiroaki Kotani ◽  
Yoshihito Shiota ◽  
Kazunari Yoshizawa ◽  
...  
Keyword(s):  
Hydrogen Bonding ◽  
Hydrogen Atom ◽  
Transition States ◽  
Adduct Formation ◽  
Hydrogen Atom Abstraction ◽  
Organic Substrates ◽  
Bond Dissociation Energies ◽  
Bond Dissociation ◽  
Dissociation Energies ◽  
Oxo Complexes

Adduct formation between Ru(iv)–oxo complexes and substrates with hydrogen bonding affords condensed transition states for substrate oxidations in water.

scholarly journals Experimental bond dissociation energies of benzylpyridinium thermometer ions determined by threshold-CID and RRKM modeling

2017 ◽  
Vol 417 ◽  
pp. 69-75 ◽  
Author(s):  
David Gatineau ◽  
Antony Memboeuf ◽  
Anne Milet ◽  
Richard B. Cole ◽  
Héloïse Dossmann ◽  
...  
Keyword(s):  
Bond Dissociation Energies ◽  
Bond Dissociation ◽  
Dissociation Energies ◽  
Thermometer Ions
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