One- and Two-Dimensional Silver-Coordination Networks Containing π-Sandwiched Silver−Silver Interactions

2002 ◽  
Vol 41 (9) ◽  
pp. 2543-2547 ◽  
Author(s):  
Eric Bosch ◽  
Charles L. Barnes
2009 ◽  
Vol 65 (3) ◽  
pp. m139-m142 ◽  
Author(s):  
Rajesh Koner ◽  
Israel Goldberg

The title compound, (5,10,15,20-tetra-4-pyridylporphyrinato)zinc(II) 1,2-dichlorobenzene disolvate, [Zn(C40H24N8)]·2C6H4Cl2, contains a clathrate-type structure. It is composed of two-dimensional square-grid coordination networks of the self-assembled porphyrin moiety, which are stacked one on top of the other in a parallel manner. The interporphyrin cavities of the overlapping networks combine into channel voids accommodated by the dichlorobenzene solvent. Molecules of the porphyrin complex are located on crystallographic inversion centres. The observed two-dimensional assembly mode of the porphyrin units represents a supramolecular isomer of the unique three-dimensional coordination frameworks of the same porphyrin building block observed earlier. The significance of this study lies in the discovery of an additional supramolecular isomer of the rarely observed structures of metalloporphyrins self-assembled directly into extended coordination polymers without the use of external ligand or metal ion auxiliaries.


2003 ◽  
Vol 42 (23) ◽  
pp. 2670-2673 ◽  
Author(s):  
Alexandre Dmitriev ◽  
Hannes Spillmann ◽  
Nian Lin ◽  
Johannes V. Barth ◽  
Klaus Kern

Polyhedron ◽  
2007 ◽  
Vol 26 (2) ◽  
pp. 385-391 ◽  
Author(s):  
Desmond Ang ◽  
Glen B. Deacon ◽  
Peter C. Junk ◽  
David R. Turner

2011 ◽  
Vol 67 (a1) ◽  
pp. C648-C648
Author(s):  
M. Quirós ◽  
A. B. Caballero ◽  
A. Rodríguez-Diéguez ◽  
J. Vieth ◽  
C. Janiak ◽  
...  

2020 ◽  
Vol 142 (47) ◽  
pp. 19814-19818
Author(s):  
Yuanyuan Guo ◽  
Ajiguli Nuermaimaiti ◽  
Niels Due Kjeldsen ◽  
Kurt V. Gothelf ◽  
Trolle R. Linderoth

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