Syntheses, Structures, and Properties of Trinuclear Complexes [M(bpca)2{M‘(hfac)2}2], Constructed with the Complexed Bridging Ligand [M(bpca)2] [M, M‘ = Ni(II), Mn(II); Cu(II), Mn(II); Fe(II), Mn(II); Ni(II), Fe(II); and Fe(II), Fe(II); Hbpca = Bis(2-pyridylcarbonyl)amine, Hhfac = Hexafluoroacetylacetone]

2002 ◽  
Vol 41 (3) ◽  
pp. 507-512 ◽  
Author(s):  
Asako Kamiyama ◽  
Tomoko Noguchi ◽  
Takashi Kajiwara ◽  
Tasuku Ito
Keyword(s):  
Bridging Ligand ◽  
Trinuclear Complexes ◽  
Structures And Properties

Heterobi- and -trinuclear Complexes with an Amino(ethynyl)carbene as Bridging Ligand

2004 ◽  
Vol 630 (12) ◽  
pp. 1863-1868 ◽  
Author(s):  
Helmut Fischer ◽  
Cornelia Hartbaum ◽  
Christiane Wespel ◽  
Markus Dede
Keyword(s):  
Bridging Ligand ◽  
Trinuclear Complexes

Characterization of chelating bis[(diphenylphosphino)methyl]phenylphosphine as a bridging ligand in bi- and trinuclear complexes

1983 ◽  
Vol 22 (16) ◽  
pp. 2223-2224 ◽  
Author(s):  
Rosalvina R. Guimerans ◽  
Marilyn M. Olmstead ◽  
Alan L. Balch
Keyword(s):  
Bridging Ligand ◽  
Trinuclear Complexes

Synthesis, Structures, Properties and DFT Studies of a New Bicopper Complexe [Cu(Hdmg)4(Hdmg)(teda)]·6H2O

2013 ◽  
Vol 470 ◽  
pp. 104-107
Author(s):  
Xuan Wen Liu ◽  
Xi Wi Qi ◽  
Feng Liu
Keyword(s):  
Solution Method ◽  
Energy Gap ◽  
Monoclinic Space Group ◽  
X Ray Diffraction ◽  
Dft Methods ◽  
Bridging Ligand ◽  
Dimethyl Glyoxime ◽  
Structures And Properties ◽  
Cu Ions ◽  
Dinuclear Structure

A new copper complexe [Cu (Hdmg)4(teda)]6H2O(H2dmg=dimethyl glyoxime;teda=triethylenediamine) was synthesized by solution method of nickel nitrate with corresponding ligands. Single crystal X-ray diffraction analysis reveals that crystal belongs to monoclinic, space group C2/c. The Cu2+ is five-coordinated with five N atoms of two dmg molecules and one teda molecule. The pdc anions, as a bridging ligand, link two adjacent Cu ions, forming a dinuclear structure. The structures and properties of complexes have been characterized by elemental analysis and IR spectrum. We also studied the electronic structure and orbital energies of the title complex by DFT methods, and the results reveals that the energy gap between LUMO and HOMO is disappeared. CCDC: 952374

Syntheses, structures and properties of three novel coordination polymers with a flexible asymmetrical bridging ligand

2006 ◽  
Vol 359 (7) ◽  
pp. 2232-2240 ◽  
Author(s):  
Lei Han ◽  
Daqiang Yuan ◽  
Benlai Wu ◽  
Caiping Liu ◽  
Maochun Hong
Keyword(s):  
Coordination Polymers ◽  
Bridging Ligand ◽  
Structures And Properties
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