Cesium(I)-Mediated 3-D Superstructures by One-Pot Self-Organization of Hydrogen-Bonded Nickel Complexes

2001 ◽  
Vol 40 (22) ◽  
pp. 5476-5478 ◽  
Author(s):  
Makoto Tadokoro ◽  
Takumasa Shiomi ◽  
Kiyoshi Isobe ◽  
Kazuhiro Nakasuji
Keyword(s):  
Nickel Complexes ◽  
Self Organization ◽  
One Pot ◽  
Hydrogen Bonded

Cation-Dependent Formation of Superstructures by One-Pot Self-Organization of Hydrogen-Bonded Nickel Complexes

1999 ◽  
Vol 38 (1-2) ◽  
pp. 95-98 ◽  
Author(s):  
Makoto Tadokoro ◽  
Kiyoshi Isobe ◽  
Hidehiro Uekusa ◽  
Yuji Ohashi ◽  
Jiro Toyoda ◽  
...  
Keyword(s):  
Nickel Complexes ◽  
Self Organization ◽  
One Pot ◽  
Hydrogen Bonded

scholarly journals A hydrogen-bonded assembly of cucurbit[6]uril and [MoO2Cl2(H2O)2] with catalytic efficacy for the one-pot conversion of olefins to alkoxy products

2019 ◽  
Vol 48 (30) ◽  
pp. 11508-11519
Author(s):  
Lucie S. Nogueira ◽  
Margarida M. Antunes ◽  
Ana C. Gomes ◽  
Luís Cunha-Silva ◽  
Martyn Pillinger ◽  
...  
Keyword(s):  
Dual Function ◽  
One Pot ◽  
Catalytic Behavior ◽  
The One ◽  
Hydrogen Bonded

A supramolecular cucurbit[6]uril/MoVI hydrogen-bonded assembly displays dual-function (oxidation/acid) catalytic behavior for the one-pot conversion of olefins to alkoxy products.

scholarly journals Self-Organization of -Crown Ether Derivatives into Double-Columnar Arrays Controlled by Supramolecular Isomers of Hydrogen-Bonded Anionic Biimidazolate Ni Complexes

2012 ◽  
Vol 2012 ◽  
pp. 1-10
Author(s):  
Makoto Tadokoro ◽  
Kyosuke Isoda ◽  
Yasuko Tanaka ◽  
Yuko Kaneko ◽  
Syoko Yamamoto ◽  
...  
Keyword(s):  
Hydrogen Bonding ◽  
Crown Ether ◽  
Building Block ◽  
The Other ◽  
Optical Isomer ◽  
Self Organization ◽  
Optical Isomers ◽  
One Dimensional ◽  
Molecular Building Block ◽  
Hydrogen Bonded

Anionic tris (biimidazolate) nickelate (II) ([Ni(Hbim)3]−), which is a hydrogen-bonding (H-bonding) molecular building block, undergoes self-organization into honeycomb-sheet superstructures connected by complementary intermolecular H-bonds. The crystal obtained from the stacking of these sheets is assembled into channel frameworks, approximately 2 nm wide, that clathrate two cationic K+-crown ether derivatives organised into one-dimensional (1D) double-columnar arrays. In this study, we have shown that all five cationic guest-included crystals form nanochannel structures that clathrate the 1-D double-columnar arrays of one of the four types of K+-crown ether derivatives, one of which induces a polymorph. This is accomplished by adaptably fitting two types of anionic [Ni(Hbim)3]−host arrays. One is a network with H-bonded linkages alternating between the two different optical isomers of the and types with flexible H-bonded [Ni(Hbim)3]−. The other is a network of a racemate with 1-D H-bonded arrays of the same optical isomer for each type. Thus, [Ni(Hbim)3]−can assemble large cations such as K+crown-ether derivatives into double-columnar arrays by highly recognizing flexible H-bonding arrangements with two host networks of and .

Self-Organization of Gold-Containing Hydrogen-Bonded Rosette Assemblies on Graphite Surface

Langmuir ◽  
2007 ◽  
Vol 23 (20) ◽  
pp. 10294-10298 ◽  
Author(s):  
Socorro Vázquez-Campos ◽  
Mária Péter ◽  
Mingdong Dong ◽  
Sailong Xu ◽  
Wei Xu ◽  
...  
Keyword(s):  
Graphite Surface ◽  
Self Organization ◽  
Hydrogen Bonded

Nanostructured Hydrogen-Bonded Rosette Assemblies Self-Assembly and Self-Organization

2005 ◽  
pp. 65-78 ◽  
Author(s):  
Mercedes Crego-Calama ◽  
David N. Reinhoudt ◽  
Juán J. García-López ◽  
Jessica M. C. A. Kerckhoffs
Keyword(s):  
Self Assembly ◽  
Self Organization ◽  
Hydrogen Bonded

[Nb6Cl12(HIm)6](OAc)2·3MeOH – a hydrogen-bonded network of niobium cluster cations, acetate anions and methanol molecules

2019 ◽  
Vol 74 (10) ◽  
pp. 751-755
Author(s):  
Eric Sperlich ◽  
Martin Köckerling
Keyword(s):  
Hydrogen Bonds ◽  
Acetic Anhydride ◽  
Title Compound ◽  
Cluster Compound ◽  
Dehydration Reaction ◽  
Coulomb Interactions ◽  
One Pot ◽  
Cluster Precursor ◽  
Additional Hydrogen ◽  
Hydrogen Bonded

AbstractThe new cluster compound [Nb6Cl12(HIm)6](OAc)2 · 3MeOH represents the first example of network compounds consisting of hexanuclear niobium cluster cations and acetate anions, which are connected though hydrogen bonds (besides Coulomb interactions). Hydrogen-bonded cation-anion pairs form chains, which are further extended to sheets by additional hydrogen bonds to co-crystallized methanol molecules. The synthesis of the title compound is based on a one-pot dehydration reaction of the cluster precursor [Nb6Cl14(H2O)4] · 4H2O with acetic anhydride in the presence of imidazole at T = 40°C.

Ligand-concentration-dependent self-organization of Hoffman- and PtS-type frameworks from one-pot crystallization

CrystEngComm ◽  
2011 ◽  
Vol 13 (19) ◽  
pp. 5666 ◽  
Author(s):  
Xin Chen ◽  
Hu Zhou ◽  
Ying-Ying Chen ◽  
Ai-Hua Yuan
Keyword(s):  
Ligand Concentration ◽  
Self Organization ◽  
One Pot

Self-Organization and Phase Behavior of Hydrogen-Bonded Mixtures of End-Functional Polymer with Surfactant

2004 ◽  
Vol 37 (3) ◽  
pp. 1152-1155 ◽  
Author(s):  
I. Akiba ◽  
H. Masunaga ◽  
K. Sasaki ◽  
Y. Jeong ◽  
K. Sakurai ◽  
...  
Keyword(s):  
Phase Behavior ◽  
Self Organization ◽  
Functional Polymer ◽  
Hydrogen Bonded
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