Crystal structures and single-crystal optical absorption spectra for two new polymorphs of tetrakis(.mu.-pivalato)dimolybdenum(II)

1990 ◽  
Vol 29 (19) ◽  
pp. 3674-3680 ◽  
Author(s):  
Don S. Martin ◽  
Hai Wei Huang
Keyword(s):  
Optical Absorption ◽  
Single Crystal ◽  
Crystal Structures ◽  
Absorption Spectra ◽  
Optical Absorption Spectra

Notizen: Preparation, Structures and Optical Properties of [H3N(CH2)6NH3]BiX5 (X=I, Cl) and [H3N(CH2)6NH3]SbX5 (X=I, Br)

1998 ◽  
Vol 53 (8) ◽  
pp. 927-932 ◽  
Author(s):  
G. A. Mousdis ◽  
G. C. Papavassiliou ◽  
A. Terzis ◽  
C. P. Raptopoulou
Keyword(s):  
Optical Properties ◽  
Optical Absorption ◽  
Crystal Structures ◽  
Absorption Spectra ◽  
Blue Shift ◽  
Optical Absorption Spectra ◽  
Absorption Bands ◽  
One Dimensional ◽  
Excitonic Absorption

Abstract The preparation, crystal structures and optical absorption spectra of [H3N(CH2)6NH3]BiX5 (X= I, Cl) and [H3N(CH2)6NH3]SbX5 (X =I, Br) are reported. The anions of the compounds consist of MX6-octahedra (M =Bi, Sb) sharing cisvertices in one-dimensional zig-zag chains. Because of their one-dimensional character, a blue shift of the excitonic absorption bands, in com parison to those of higher dim ensionality systems (MX3), is observed.

scholarly journals A New Type of 1-D Thioindates, [M(en)3]0.5[InS2] (M = Co, Ni), Synthesized by Solvothermal Reaction

2009 ◽  
Vol 64 (5) ◽  
pp. 504-508 ◽  
Author(s):  
Jian Zhou ◽  
Yong Zhang ◽  
Ming-Hui Zhang ◽  
Zhi-Xin Lei ◽  
Jie Dai
Keyword(s):  
Optical Absorption ◽  
Crystal Structures ◽  
Absorption Spectra ◽  
Band Gaps ◽  
Solvothermal Reaction ◽  
Optical Absorption Spectra ◽  
Orthorhombic Space Group ◽  
Space Group ◽  
New Type ◽  
Solvothermal Conditions

Two thioindates [M(en)3]0.5InS2 [en = ethylenediamine; M = Ni (1), Co (2)] were prepared by the reaction of In2S3, Ni (or Co) and S under solvothermal conditions, and their crystal structures have been determined. Both compounds are isostructural and crystallize in the orthorhombic space group Cmcm. The crystal structures consist of a new type of 1-D sinusoidal chain, which complements the reported I - III types of 1-D [InQ2−]n (Q = S, Te) anions built from InQ4 tetrahedra. The band gaps of 3.47 eV for I and 3.31 eV for 2 have been derived from optical absorption spectra.

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