Electrochemical polymerization of 4-methyl-4'-vinyl-2,2'-bipyridine-containing metal complexes: polymer structure and mechanism of formation

1990 ◽  
Vol 29 (3) ◽  
pp. 389-392 ◽  
Author(s):  
C. Michael Elliott ◽  
Christopher J. Baldy ◽  
Lydia M. Nuwaysir ◽  
Charles L. Wilkins
Keyword(s):  
Metal Complexes ◽  
Electrochemical Polymerization ◽  
Polymer Structure ◽  
Mechanism Of Formation

Mechanism of formation ofo-semiquinone metal complexes under mechanical pulse action on metal oxide-quinone-pyrocatechol systems

1999 ◽  
Vol 48 (2) ◽  
pp. 323-329 ◽  
Author(s):  
A. I. Aleksandrov ◽  
A. I. Prokof'ev ◽  
N. N. Bubnov ◽  
R. R. Rakhimov ◽  
I. A. Aleksandrov ◽  
...  
Keyword(s):  
Metal Oxide ◽  
Metal Complexes ◽  
Pulse Action ◽  
Mechanism Of Formation ◽  
Mechanical Pulse

Enhancement of Schiff base biological efficacy by metal coordination and introduction of metallic compounds as anticovid candidates: a simple overview

2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Jan Mohammad Mir ◽  
Sheikh Abdul Majid ◽  
Aabid Hussain Shalla
Keyword(s):  
Schiff Base ◽  
Metal Complexes ◽  
Antimicrobial Properties ◽  
Biological Evaluation ◽  
Organic Ligands ◽  
Molecular Scaffolds ◽  
Mechanism Of Formation ◽  
Biological Efficacy ◽  
Metallic Compounds ◽  
Azomethine Compounds

Abstract In the prevailing apocalyptic times of coronavirus disease (COVID-19), the whole scientific community is busy in designing anticovid drug or vaccine. Under such a fascination, Schiff bases or azomethine compounds are continuously interrogated for antimicrobial properties. These compounds represent interesting molecular scaffolds of huge medicinal and industrial relevance. In order to update the current literature support of such facts this article introduces the synthetic chemistry, mechanism of formation of a Schiff base, followed by biological efficacy and finally a suitable discussion on the mechanism of respective bioactivity. In most of the studies revealing the biological evaluation of azomethine functionalized frameworks, fascinated results have been recorded in case of azomethine-metal complexes as compared with the free ligands. Also, the CH=N or C=N form of organic ligands have indicated marvellous results. Therefore, in connection with the biological relevance and microbicidal implications of such metallic compounds, this works reviews the current update of microorganism fighting efficacy of azomethine metal complexes along with the introduction of some metallodrugs as excellent candidates having COVID-19 defending potentiality.

Mechanochemical changes on cyclometalated Ir(iii) acyclic carbene complexes – design and tuning of luminescent mechanochromic transition metal complexes

2020 ◽  
Vol 7 (3) ◽  
pp. 786-794 ◽  
Author(s):  
Jingqi Han ◽  
Kin-Man Tang ◽  
Shun-Cheung Cheng ◽  
Chi-On Ng ◽  
Yuen-Kiu Chun ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Carbene Complexes ◽  
New Class

A new class of luminescent cyclometalated Ir(iii) complexes with readily tunable mechanochromic properties derived from the mechanically induced trans-to-cis isomerization have been developed.

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