Carbon monoxide labilization and hydrogen-transfer pathways in cationic phosphido-bridged rhenium-platinum heterobimetallic systems and the molecular structures of [.eta.5-Cp(ON)Re(.mu.-PR2)(.mu.-H)Pt(PPh3)2]X (R = Cy, X- = PF6-; R = Ph, X- = BF4) and [.eta.5-Cp(ON)HRe(.mu.-PCy2)Pt(PPh3)2]BF4, a rare example of bridging- and terminal-hydrido geometric isomers

1989 ◽  
Vol 28 (25) ◽  
pp. 4461-4470 ◽  
Author(s):  
John Powell ◽  
Jeffery F. Sawyer ◽  
Matthew V. R. Stainer
Keyword(s):  
Carbon Monoxide ◽  
Hydrogen Transfer ◽  
Molecular Structures ◽  
Geometric Isomers

Reductive intramolecular hydrogen transfer in a d8 metal hydride promoted by carbon monoxide addition. An experimental study and its theoretical implications

1984 ◽  
Vol 23 (7) ◽  
pp. 922-929 ◽  
Author(s):  
Franco Cecconi ◽  
Carlo A. Ghilardi ◽  
Paolo Innocenti ◽  
Carlo Mealli ◽  
Stefano Midollini ◽  
...  
Keyword(s):  
Experimental Study ◽  
Carbon Monoxide ◽  
Metal Hydride ◽  
Hydrogen Transfer ◽  
Intramolecular Hydrogen

Isolation, crystal and molecular structures of two geometric isomers of a 3N, 2S pentacoordinate copper(II) complex

1987 ◽  
Vol 26 (14) ◽  
pp. 2194-2196 ◽  
Author(s):  
Richard S. Glass ◽  
Mahmood Sabahi ◽  
Massoud Hojjatie ◽  
George S. Wilson
Keyword(s):  
Molecular Structures ◽  
Geometric Isomers ◽  
Crystal And Molecular Structures

Carbon monoxide release properties and molecular structures of phenylthiolatomanganese(i) carbonyl complexes of the type [(OC)4Mn(μ-S-aryl)]2

2015 ◽  
Vol 44 (7) ◽  
pp. 3020-3033 ◽  
Author(s):  
Ralf Mede ◽  
Vaneza Paola Lorett-Velásquez ◽  
Moritz Klein ◽  
Helmar Görls ◽  
Michael Schmitt ◽  
...  
Keyword(s):  
Carbon Monoxide ◽  
Ligand Exchange ◽  
Molecular Structures ◽  
Carbonyl Complexes

Arylthiolatomanganese(i) tetracarbonyls form dimers or trimers and show a two-step CO release, triggered by ligand exchange and irradiation.

Metal Complexes of an Ionic Liquid-Derived Carbene

2011 ◽  
Vol 64 (8) ◽  
pp. 1133 ◽  
Author(s):  
Marcus L. Cole ◽  
Matthew R. Gyton ◽  
Jason B. Harper
Keyword(s):  
Carbon Monoxide ◽  
Ionic Liquid ◽  
Metal Complexes ◽  
Silver Salt ◽  
Ligand Substitution ◽  
Molecular Structures ◽  
Direct Reaction ◽  
Metal Acetate ◽  
Carbene Complexes ◽  
Hydrochloride Salt

A range of metal carbene complexes containing the ionic liquid-derived N-heterocyclic carbene (NHC) 1-nbutyl-3-methylimidazol-2-ylidene (IBuMe, 1) have been prepared by (i) direct ligand substitution using the free NHC ([Mo(CO)5(IBuMe)] 2), (ii) transmetallation using the silver salt [AgCl(IBuMe)] (3) ([RhCl(NBD)(IBuMe)] (4) and [IrCl(COD)(IBuMe)] (5), NBD = 2,5-norbornadiene, COD = 1,5-cyclooctadiene) and (iii) direct reaction of a metal acetate with the hydrochloride salt of 1 (trans-[PdCl2(IBuMe)] (6)). The dicarbonyl cis-[RhCl(CO)2(IBuMe)] (7) has been prepared by diene substitution under a carbon monoxide atmosphere. The molecular structures of 2, 4, 5 and 6 are reported and the sigma donation and steric properties of 1 are discussed relative to those of common imidazol-2-ylidene ligands.

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