Coordination chemistry and redox properties of polypyridyl complexes of vanadium(II)

1989 ◽  
Vol 28 (7) ◽  
pp. 1310-1315 ◽  
Author(s):  
John C. Dobson ◽  
Henry Taube
Keyword(s):  
Coordination Chemistry ◽  
Redox Properties ◽  
Polypyridyl Complexes

Redox Properties of Iron Complexes with Pentadentate Bispidine Ligands

2014 ◽  
Vol 67 (3) ◽  
pp. 398 ◽  
Author(s):  
Peter Comba ◽  
Hubert Wadepohl ◽  
Arkadius Waleska
Keyword(s):  
Aqueous Solution ◽  
Cyclic Voltammetry ◽  
Coordination Chemistry ◽  
Aqueous Solutions ◽  
Iron Complexes ◽  
Redox Properties

The solution coordination chemistry of iron complexes with the pentadentate bispidine ligands L1, L2, and L3 (dimethyl 9-oxo-2,4-di(pyridin-2-yl)-3,7-diazabicyclo[3.3.1]nonane-1,5-dicarboxylate derivatives) was examined. While in acetonitrile, (L1,2)FeII/III species have a preference for Cl– as co-ligand. The corresponding aqua and hydroxido complexes also prevail in the presence of Cl– in aqueous solution. The observed FeII/III potentials in water (cyclic voltammetry) and potentials of (L1–3)FeIV=O (buffered and unbuffered aqueous solutions) are strikingly similar, i.e. the latter are assigned to (L1–3)FeII/III potentials, and published potentials of FeIV=O complexes with other ligands with uncharged amine-pyridine donors, obtained by cyclic voltammetry, have to be considered with caution.

scholarly journals Photophysical and Redox Properties of Dinuclear Ru and Os Polypyridyl Complexes with Incorporated Photostable Spiropyran Bridge

2009 ◽  
Vol 48 (4) ◽  
pp. 1711-1721 ◽  
Author(s):  
Ron T. F. Jukes ◽  
Biljana Bozic ◽  
Peter Belser ◽  
Luisa De Cola ◽  
František Hartl
Keyword(s):  
Redox Properties ◽  
Polypyridyl Complexes

Areneruthenium(II) 4-Acyl-5-pyrazolonate Derivatives:  Coordination Chemistry, Redox Properties, and Reactivity

2007 ◽  
Vol 46 (20) ◽  
pp. 8245-8257 ◽  
Author(s):  
Fabio Marchetti ◽  
Claudio Pettinari ◽  
Riccardo Pettinari ◽  
Adele Cerquetella ◽  
Augusto Cingolani ◽  
...  
Keyword(s):  
Coordination Chemistry ◽  
Redox Properties

scholarly journals Coordination Chemistry of a Strongly-Donating Hydroxylamine with Early Actinides: An Investigation of Redox Properties and Electronic Structure

2018 ◽  
Vol 57 (8) ◽  
pp. 4387-4394 ◽  
Author(s):  
Alex McSkimming ◽  
Jing Su ◽  
Thibault Cheisson ◽  
Michael R. Gau ◽  
Patrick J. Carroll ◽  
...  
Keyword(s):  
Electronic Structure ◽  
Coordination Chemistry ◽  
Redox Properties

Coordination Chemistry of Low-Valent Rhenium Polypyridyl Complexes:  Synthesis, Reactivity, and Electrochemistry†

1996 ◽  
Vol 35 (19) ◽  
pp. 5584-5594 ◽  
Author(s):  
Lisa E. Helberg ◽  
Stephen D. Orth ◽  
Michal Sabat ◽  
W. Dean Harman
Keyword(s):  
Coordination Chemistry ◽  
Polypyridyl Complexes ◽  
Low Valent

Urea Azines (Bisguanidines): Electronic Structure, Redox Properties, and Coordination Chemistry

2015 ◽  
Vol 2015 (13) ◽  
pp. 2345-2361 ◽  
Author(s):  
Hendrik Herrmann ◽  
Matthias Reinmuth ◽  
Sven Wiesner ◽  
Olaf Hübner ◽  
Elisabeth Kaifer ◽  
...  
Keyword(s):  
Electronic Structure ◽  
Coordination Chemistry ◽  
Redox Properties
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