Metalloporphyrins with metal-metal bonds. Synthesis, characterization, and electrochemistry of (P)TlMn(CO)5, (P)TlCo(CO)4, and (P)TlM(CO)3Cp where M = Cr, Mo, and W. Crystal structure of [(2,3,7,8,12,13,17,18-octaethylporphinato)thallium(III)]pentacarbonylmanganese

1988 ◽  
Vol 27 (4) ◽  
pp. 697-705 ◽  
Author(s):  
R. Guilard ◽  
A. Zrineh ◽  
M. Ferhat ◽  
A. Tabard ◽  
P. Mitaine ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Metal Metal ◽  
Metal Metal Bonds ◽  
Metal Bonds

Öffnung von Dreikernclustern durch Diphosphinomethan-Liganden / Opening of Trinuclear Clusters by Diphosphinomethane Ligands

1989 ◽  
Vol 44 (2) ◽  
pp. 139-144 ◽  
Author(s):  
Roy P. Planalp ◽  
Heinrich Vahrenkamp
Keyword(s):  
Crystal Structure ◽  
Structure Determination ◽  
Addition Product ◽  
Crystal Structure Determination ◽  
Metal Metal ◽  
Trinuclear Clusters ◽  
Metal Metal Bonds ◽  
Metal Bonds

Abstract The phosphinidene bridged clusters FeCo2(CO)9(PMe) and FeCoWCp(CO)8(PM e) add the diphosphinomethane ligands dmpm and dppm with concomitant opening of two metal-metal bonds. The crystal structure determination of the addition product (Me2P-CH2-PMe2)FeCoWCp(CO)8(PMe) has shown that the Fe -W and Fe -Co bonds have been opened and the chelating diphosphine spans the Co -W bond. This is in contrast to the reaction with monodentate phosphines where the Co -W and Co -Fe bonds are broken. Upon heating the addition products eliminate two moles of CO with formation of the diphos­ phinom ethane substituted starting clusters, which in turn add CO under pressure to re-form the addition products.

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