Bromine oxidation of a nickel(II) bis(oxime-imine) complex. Evidence for a single-step outer-sphere two-electron transfer?

1987 ◽  
Vol 26 (19) ◽  
pp. 3089-3094 ◽  
Author(s):  
A. Graham Lappin ◽  
Peter Osvath ◽  
Subhash Baral
Keyword(s):  
Electron Transfer ◽  
Outer Sphere ◽  
Single Step

scholarly journals RuIII(edta) complexes as molecular redox catalysts in chemical and electrochemical reduction of dioxygen and hydrogen peroxide: inner-sphere versus outer-sphere mechanism

RSC Advances ◽  
2021 ◽  
Vol 11 (35) ◽  
pp. 21359-21366
Author(s):  
Debabrata Chatterjee ◽  
Marta Chrzanowska ◽  
Anna Katafias ◽  
Maria Oszajca ◽  
Rudi van Eldik
Keyword(s):  
Hydrogen Peroxide ◽  
Electron Transfer ◽  
Electrochemical Reduction ◽  
Molecular Oxygen ◽  
Outer Sphere ◽  
Transfer Processes ◽  
Edta Complexes ◽  
Inner Sphere ◽  
Electron Transfer Processes ◽  
Sphere Mechanism

[RuII(edta)(L)]2–, where edta4– =ethylenediaminetetraacetate; L = pyrazine (pz) and H2O, can reduce molecular oxygen sequentially to hydrogen peroxide and further to water by involving both outer-sphere and inner-sphere electron transfer processes.

Outer-sphere electron transfer between (cyclam)nickel(2+) and copper(III) imine-oxime complexes

1989 ◽  
Vol 28 (1) ◽  
pp. 157-160 ◽  
Author(s):  
Ashiq Hussein ◽  
Yousif Sulfab ◽  
Mohamed Nasreldin
Keyword(s):  
Electron Transfer ◽  
Outer Sphere ◽  
Outer Sphere Electron Transfer
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