Electronic and vibrational spectra of Ru2(carboxylate)4 + complexes. Characterization of a high-spin metal-metal ground state

1987 ◽  
Vol 26 (7) ◽  
pp. 1098-1108 ◽  
Author(s):  
Vincent M. Miskowski ◽  
Thomas M. Loehr ◽  
Harry B. Gray
Keyword(s):  
High Spin ◽  
Vibrational Spectra ◽  
Ground State ◽  
Metal Metal ◽  
Electronic And Vibrational Spectra

The Isolation and Characterization of Square Planar, Square Pyramidal, and Octahedral Copper(II) Complexes with Mixed Ligands

1978 ◽  
Vol 33 (8) ◽  
pp. 906-910 ◽  
Author(s):  
M. M. Aly
Keyword(s):  
Vibrational Spectra ◽  
Dichloroacetic Acid ◽  
Chemical Analyses ◽  
Cleavage Reaction ◽  
Mixed Ligands ◽  
Isolation And Characterization ◽  
Square Planar ◽  
Electronic And Vibrational Spectra ◽  
Heterocyclic Bases

Substitution of an acetylacetonate by a carboxylate in the neutral (acac)2Cu(II) was achieved by its reaction with tri- and dichloroacetic acid in benzene (HCO2R where R = CCl3 or CHCl2; Hacac = acetylacctone) which led to the formation of the mixed chelate square planar complex (acac)Cu(OCOR). The later complex, R = CCl3, reacted with heterocyclic bases to produce the square pyramidal complexes (acac)Cu(OCOR) (base), (base = 2- methylpyridine or quinoline); with ethylenediamine (en) to give the octahedral [(en)2Cu(OCOR)]Cl, and with methanol and piperidine or boiling methanol alone to give the methoxo-bridged (acac)Cu(OCH3)2Cu(acac). The reaction of acetylacetonate-carboxy- late-copper(II) complex (R = CHCl2) with heterocyclic bases led to the cleavage of the acetylacetonate ligand and the formation of the octahedral Cu(OCOCHCl2) · 2 base (base = pyridine, 2-, 3- or 4-methylpyridine). The same cleavage reaction took place, and also with R = CCl3, in their reaction with 8-hydroxyquinoline to form the mixed chelates (ROCO)Cu(Oxinate). These formulations are based on chemical analyses, electronic and vibrational spectra, and on conductance measurements.

scholarly journals Synthesis and characterization of [7]triangulene

Nanoscale ◽  
2021 ◽  
Author(s):  
Shantanu Mishra ◽  
Kun Xu ◽  
Kristjan Eimre ◽  
Hartmut Komber ◽  
Ji Ma ◽  
...  
Keyword(s):  
High Spin ◽  
Ground States ◽  
Synthesis And Characterization ◽  
Spintronic Devices

Triangulene and its π-extended homologues constitute non-Kekulé polyradical frameworks with high-spin ground states, and are anticipated to be key components of organic spintronic devices. We report a combined in-solution and...

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