Polyfluoroalkyl dibasic acid phosphates, bis(polyfluoroalkyl) monobasic acid phosphates, and their precursors

1986 ◽  
Vol 25 (21) ◽  
pp. 3830-3837 ◽  
Author(s):  
Tariq Mahmood ◽  
Jean'ne M. Shreeve
Keyword(s):  
1974 ◽  
Vol 143 (3) ◽  
pp. 775-777 ◽  
Author(s):  
John L. Wood

The pH-dependence of the degree of hydrogen-bonding between a base and its conjugate acid is considered. When only a small proportion of the total base is complexed, the amount complexed is proportional to (1+coshp)−1 where p=2.303 (pKa–pH), pKa being the dissociation constant of the conjugate acid. This represents sharp pH-dependence. As the proportion complexed increases, the curve broadens, eventually becoming flat-topped, with more than half the base complexed over the range of pH values pKa±logKC, approximately. (K is the complex association constant and C is the formal base concentration, including all forms.) There are similarities to the extent of mono-protonation of a dibasic acid.


1983 ◽  
Vol 20 (1) ◽  
pp. 87-91 ◽  
Author(s):  
Masayuki Sato ◽  
Hiromichi Ogasawara ◽  
Tetsuzo Kato
Keyword(s):  

1955 ◽  
Vol 33 (9) ◽  
pp. 1450-1451 ◽  
Author(s):  
M. P. Gupta

not available


1983 ◽  
Vol 14 (36) ◽  
Author(s):  
M. SATO ◽  
H. OGASAWARA ◽  
T. KATO
Keyword(s):  

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