Variable-temperature platinum-195 NMR spectroscopy, a new technique for the study of stereodynamics. Sulfur inversion in a platinum(II) complex with methionine

1986 ◽  
Vol 25 (14) ◽  
pp. 2429-2433 ◽  
Author(s):  
David D. Gummin ◽  
Eva Marie A. Ratilla ◽  
Nenad M. Kostic
1990 ◽  
Vol 180 ◽  
Author(s):  
Young J. Chung ◽  
Su-Jen Ting ◽  
John D. Mackenzie

ABSTRACTA new technique which permits the successful preparation of ORMOSILS (Organically Modified Silicates) with rubbery elasticity has been developed. Common alkoxides were reacted with polydimethyl siloxane (PDMS) and the microstructures were carefully controlled. Large monoliths of the porous rubbery ORMOSILS have been prepared. Gelation process was studied by 29Si liquid NMR spectroscopy. A structural model for rubber elasticity of ORMOSILS was proposed.


1986 ◽  
Vol 68 (2) ◽  
pp. 367-372 ◽  
Author(s):  
David M Doddrell ◽  
William M Brooks ◽  
J.Mark Bulsing ◽  
James Field ◽  
Michael G Irving ◽  
...  

1986 ◽  
Vol 70 (2) ◽  
pp. 319-326 ◽  
Author(s):  
David M Doddrell ◽  
J.Mark Bulsing ◽  
Graham J Galloway ◽  
William M Brooks ◽  
James Field ◽  
...  

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