A tetraphosphorus chain as part of a P8-containing ligand. Synthesis and properties of the .eta.4-phosphabutadiene cobalt complex [Co(Ph2PCH2P(Ph)2P4P(Ph)2CH2PPh2)]BF4 and of its carbonyl derivatives {[Co(Ph2PCH2P(Ph)2P4P(Ph)2CH2PPh2)][Cr(CO)5]2}BF4 and {[Co(Ph2PCH2P(Ph)2P4P(Ph)2CH2PPh2)][W(CO)5]}Y (Y = BPh4, BF4). X-ray crystal structure of [Co(Ph2PCH2P(Ph)2P4P(Ph)2CH2PPh2)]BF4

1986 ◽  
Vol 25 (11) ◽  
pp. 1766-1770 ◽  
Author(s):  
Franco Cecconi ◽  
Carlo A. Ghilardi ◽  
Stefano Midollini ◽  
Annabella Orlandini
2013 ◽  
Vol 23 (3) ◽  
pp. 135-136 ◽  
Author(s):  
Ekaterina A. Trofimova ◽  
Alexey B. Dobrynin ◽  
Tatiana P. Gerasimova ◽  
Sergey A. Katsyuba ◽  
Oleg G. Sinyashin ◽  
...  

Polyhedron ◽  
2015 ◽  
Vol 93 ◽  
pp. 99-105 ◽  
Author(s):  
S. Yousef Ebrahimipour ◽  
Iran Sheikhshoaie ◽  
Anna Christin Kautz ◽  
Mojgan Ameri ◽  
Hamzeh Pasban-Aliabadi ◽  
...  

2009 ◽  
Vol 64 (8) ◽  
pp. 985-988 ◽  
Author(s):  
Jian-Qiang Wang ◽  
Thomas F. Fässler

The cobalt complex [{K(18-crown-6)}2(C5H5)]- [Co(C8H12)2]・(THF)2 (3) has been synthesized and characterized by X-ray single-crystal structure determination. The crystal structure of Co(C8H12)(C8H13) (2) has been reinvestigated and compared with the structure of 3. The 1,5-cyclooctadiene (C8H12) and C8H13 ligands are coordinated in an η4 and η3 fashion, respectively. The cyclopentadienyl anion in [{K(18-crown-6)}2(C5H5)]+ in 3 is η5-coordinated to the two crown ether-encapsulated potassium cations


Sign in / Sign up

Export Citation Format

Share Document