Cyclometalated complexes of ruthenium. 2. Spectral and electrochemical properties and x-ray structure of bis(2,2'-bipyridine)(4-nitro-2-(2-pyridyl)phenyl)ruthenium(II)

1985 ◽  
Vol 24 (24) ◽  
pp. 4078-4082 ◽  
Author(s):  
P. Reveco ◽  
R. H. Schmehl ◽  
W. R. Cherry ◽  
F. R. Fronczek ◽  
J. Selbin
Keyword(s):  
Electrochemical Properties ◽  
X Ray ◽  
Cyclometalated Complexes ◽  
Spectral And Electrochemical Properties

Synthesis and characterization of periphery-functionalized porphyrazines containing mixed pyrrolyl and pyridylmethylamino groups

2009 ◽  
Vol 13 (02) ◽  
pp. 223-234 ◽  
Author(s):  
Tomasz Goslinski ◽  
Ewa Tykarska ◽  
Wojciech Szczolko ◽  
Tomasz Osmalek ◽  
Aleksandra Smigielska ◽  
...  
Keyword(s):  
Electrochemical Properties ◽  
Chemical Sensors ◽  
Electronic Materials ◽  
Condensation Reaction ◽  
Synthesis And Characterization ◽  
X Ray ◽  
Coordination Properties ◽  
Perpendicular Orientation ◽  
Selective Sensor

The condensation reaction of 2-amino-3-[(3-pyridylmethyl)amino]-2(Z)-butene-1,4-dinitrile with a series of diketones led to novel dinitriles, of which 2-(2,5-dimethyl-1H-pyrrol-1-yl)-3-[methyl(3-pyridylmethylene)amino]-2(Z)-butene-1,4-dinitrile, the product of the Paal-Knorr reaction, was successfully utilized in the Linstead macrocyclization towards symmetrical and unsymmetrical porphyrazines. NMR and X-ray study revealed an almost perpendicular orientation of the pyrrolyl groups in relation to the porphyrazine platform. The newly synthesized macrocycles with different peripheral groups show interesting spectroscopic and electrochemical properties. Due to selective sensor/coordination properties they are expected to find applications as chemical sensors and electronic materials.

Probing Structure Modification of Palladium Nanomaterials during Chemical Synthesis by using In Situ X-ray Diffraction: Electrochemical Properties

2015 ◽  
Vol 2 (4) ◽  
pp. 592-599 ◽  
Author(s):  
Yaovi Holade ◽  
Teko W. Napporn ◽  
Claudia Morais ◽  
Karine Servat ◽  
K. Boniface Kokoh
Keyword(s):  
Chemical Synthesis ◽  
Electrochemical Properties ◽  
Structure Modification ◽  
X Ray Diffraction ◽  
X Ray
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