EPR spectra of low-symmetry tetrahedral high-spin cobalt(II) in a cinchoninium tetrachlorocobaltate(II) dihydrate single crystal

1985 ◽  
Vol 24 (24) ◽  
pp. 4009-4012 ◽  
Author(s):  
H. Drulis ◽  
K. Dyrek ◽  
K. P. Hoffmann ◽  
Stanislaw K. Hoffmann ◽  
A. Weselucha-Birczynska
Keyword(s):  
Single Crystal ◽  
High Spin ◽  
Epr Spectra ◽  
Low Symmetry

ChemInform Abstract: EPR Spectra of Low-Symmetry Tetrahedral High-Spin Cobalt(II) in a Cinchoninium Tetrachlorocobaltate(II) Dihydrate Single Crystal.

1986 ◽  
Vol 17 (11) ◽  
Author(s):  
H. DRULIS ◽  
K. DYREK ◽  
K. P. HOFFMANN ◽  
S. K. HOFFMANN ◽  
A. WESELUCHA-BIRCZYNSKA
Keyword(s):  
Single Crystal ◽  
High Spin ◽  
Epr Spectra ◽  
Low Symmetry

Single-crystal EPR spectra of the high-spin [Co(TMC)(CH3CN))](ClO2)2 complex

1990 ◽  
Vol 171 (1-2) ◽  
pp. 114-118
Author(s):  
Mark Wicholas ◽  
Claudia Zanchini
Keyword(s):  
Single Crystal ◽  
High Spin ◽  
Epr Spectra

Properties of electrochemically generated primary cationradicals of phenyl- and 2-(4-tolyl)-1,3,4,7-tetramethylisoindoles

1980 ◽  
Vol 45 (6) ◽  
pp. 1669-1676 ◽  
Author(s):  
Pavel Kubáček
Keyword(s):  
Electrochemical Oxidation ◽  
Spin Polarization ◽  
High Spin ◽  
Epr Spectroscopy ◽  
Half Life ◽  
Electrochemical Behaviour ◽  
Epr Spectra ◽  
Electrochemical Generation ◽  
Splitting Constant ◽  
Reduced Temperature

The first step of electrochemical oxidation of 2-phenyl- and 2-(4-tolyl)-1,3,4,7-tetramethylisoindoles in anhydrous acetonitrile produces relatively stable cationradicals which have been studied by means of EPR spectroscopy using the method of internal electrochemical generation of radicals under reduced temperature. The same electrochemical behaviour of the both studied derivatives and identical EPR spectra of their cationradicals can be explained within the Huckel MO method. The largest contribution to the magnitude of splitting constant of nitrogen nucleus is due to π-σ-spin polarization of C-N bonds caused by high spin abundance of pz-AO of carbon atoms. Half-life of decomposition of the studied cationradicals is 4 min at -30°C.

Nature of the Coupling between the High-Spin Fe(III) Heme and CuB(II) in the Active Site of Terminal Oxidases:  Dual-Mode EPR Spectra of Fluoride Cytochromebo3

1998 ◽  
Vol 120 (17) ◽  
pp. 4232-4233 ◽  
Author(s):  
Vasily S. Oganesyan ◽  
Clive S. Butler ◽  
Nicholas J. Watmough ◽  
Colin Greenwood ◽  
Andrew J. Thomson ◽  
...  
Keyword(s):  
High Spin ◽  
Active Site ◽  
Epr Spectra ◽  
Dual Mode ◽  
Terminal Oxidases

Metal-nitroxyl interactions. 37. Single-crystal EPR spectra of a spin-labeled copper complex containing an imine-urea linkage

1984 ◽  
Vol 23 (10) ◽  
pp. 1326-1330 ◽  
Author(s):  
Reddy Damoder ◽  
Kundalika M. More ◽  
Gareth R. Eaton ◽  
Sandra S. Eaton
Keyword(s):  
Single Crystal ◽  
Copper Complex ◽  
Epr Spectra
Sign in / Sign up

Export Citation Format

Share Document