Tertiary phosphine complexes of gold(I) and gold(III) with imido ligands: 1H, 31P, and 15N NMR spectroscopy, antiinflammatory activity, and x-ray crystal structure of (phthalimido)(triethylphosphine)gold(I)

1985 ◽  
Vol 24 (21) ◽  
pp. 3425-3434 ◽  
Author(s):  
Susan J. Berners Price ◽  
Michael J. DiMartino ◽  
David T. Hill ◽  
Reiko Kuroda ◽  
Muhammed A. Mazid ◽  
...  
2019 ◽  
Vol 10 (26) ◽  
pp. 6431-6436 ◽  
Author(s):  
Selena L. Staun ◽  
Dumitru-Claudiu Sergentu ◽  
Guang Wu ◽  
Jochen Autschbach ◽  
Trevor W. Hayton

The first isolable molecular thorium nitride, [(NR2)3Th(μ-N)Th(NR2)3]−, was synthesized by reaction of [Th{N(R)(SiMe2)CH2}(NR2)2] with NaNH2 and characterized by X-ray crystallography, 15N NMR spectroscopy, and DFT calculations.


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