Coordination modes of polydentate ligands. 3. Five-coordinate complexes of cobalt(2+), copper(2+), and nickel(2+) containing a tridentate thioether-alkoxy ligand

1985 ◽  
Vol 24 (4) ◽  
pp. 593-597 ◽  
Author(s):  
Rene T. Boere ◽  
W. Mark Brown ◽  
Douglas W. Stephan ◽  
Christopher J. Willis
1982 ◽  
Vol 21 (1) ◽  
pp. 20
Author(s):  
Edward Konefal ◽  
Stephen J. Loeb ◽  
Christopher J. Willis

2008 ◽  
Vol 59 (11) ◽  
Author(s):  
Mircea Braban ◽  
Ionel Haiduc

The paper describes the solid state structure of a compound of composition [Cu(bipy)3][Cu(bipy)(ala) (ClO4)2]ClO4, in which both the cation and anion are octahedral complex species with copper(II) as coordination center. The cation contains three chelate rings formed by bipy; the anion contains in the quatorial plane a CuONC2 chelate ring formed by the alaninato ligand and a CuN2C2 chelate ring formed by bipy, with two monodentate perchorato ligands in axial positions completing the six-coordination. In the crystal p-p stackings lead to a supramolecular self-assembled structure.


Sign in / Sign up

Export Citation Format

Share Document