Kinetics of oxygen atom transfer reactions involving oxomolybdenum complexes. General treatment for reactions with intermediate oxo-bridged molybdenum(V) dimer formation

1984 ◽  
Vol 23 (20) ◽  
pp. 3057-3062 ◽  
Author(s):  
Martha S. Reynolds ◽  
Jeremy M. Berg ◽  
Richard H. Holm
Author(s):  
Leila G. Ranis ◽  
Jacqueline Gianino ◽  
Justin M. Hoffman ◽  
Seth N. Brown

Eight-coordinate MoO2(DOPOQ)2 can donate two oxygen atoms to substrates such as phosphines in a four-electron nonclassical oxygen atom transfer reaction.


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