Identification of the zinc reduction product of VCl3.3THF as [V2Cl3(THF)6]2[Zn2Cl6]

1984 ◽  
Vol 23 (17) ◽  
pp. 2715-2718 ◽  
Author(s):  
Reinder J. Bouma ◽  
Jan H. Teuben ◽  
W. R. Beukema ◽  
Rick L. Bansemer ◽  
John C. Huffman ◽  
...  
Keyword(s):  
Reduction Product ◽  
Zinc Reduction

ChemInform Abstract: IDENTIFICATION OF THE ZINC REDUCTION PRODUCT OF VCL3.3THF AS (V2CL3(THF)6)2(ZN2CL6)

1984 ◽  
Vol 15 (47) ◽  
Author(s):  
R. J. BOUMA ◽  
J. H. TEUBEN ◽  
W. R. BEUKEMA ◽  
R. L. BANSEMER ◽  
J. C. HUFFMAN ◽  
...  
Keyword(s):  
Reduction Product ◽  
Zinc Reduction

scholarly journals Isolation, Structure Elucidation, and Biological Activity of a New Alkaloid from Zanthoxylum rhetsa

2011 ◽  
Vol 6 (11) ◽  
pp. 1934578X1100601
Author(s):  
Karsten Krohn ◽  
Stephan Cludius-Brandt ◽  
Barbara Schulz ◽  
Mambatta Sreelekha ◽  
Pottachola Mohamed Shafi
Keyword(s):  
Biological Activity ◽  
Carboxylic Acid ◽  
Medicinal Plant ◽  
Plant Extract ◽  
Structure Elucidation ◽  
Biologically Active ◽  
Reduction Product ◽  
Pharmacological Properties ◽  
Evergreen Tree

Several biologically active alkaloids (1-4, 6), including a new quinazoline-6-carboxylic acid (1), were isolated from the medicinal plant Zanthoxylum rhetsa, an evergreen tree, native to subtropical areas. Whereas the pharmacological properties of the plant extract and single constituents have been widely tested, we now show that all of the metabolites have antialgal activities, all but 6 are antibacterial, and 6 and the reduction product 5 (derived from 4) are also antifungal.

Sintering of NbTa powders from aluminothermic reduction product (ATR)

1992 ◽  
Vol 11 (1) ◽  
pp. 43-47
Author(s):  
Uilame Umbelino Gomes ◽  
Angelus Guiseppe Pereira da Silva ◽  
Jose Nilson Franca de Holanda ◽  
Daltro Garcia Pinatti
Keyword(s):  
Aluminothermic Reduction ◽  
Reduction Product

The detection of a radical step in the zinc reduction of bromocyclopropanes

1984 ◽  
Vol 33 (11) ◽  
pp. 2435-2435
Author(s):  
A. I. D'yachenko ◽  
O. S. Korneva ◽  
O. M. Nefedov
Keyword(s):  
Zinc Reduction

2-Epi- and 15-dihydro-2-epilubimin: new stress compounds from the potato

1980 ◽  
Vol 58 (19) ◽  
pp. 2069-2072 ◽  
Author(s):  
A. Stoessl ◽  
J. B. Stothers
Keyword(s):  
Magnetic Resonance ◽  
Pathogenic Fungus ◽  
Reduction Product ◽  
Magnetic Resonance Data ◽  
Resonance Data

The complement of sesquiterpenoidal stress compounds produced in the interaction of potato with the pathogenic fungus, Alternariasolani, includes representatives of a new stereochemical series, 2-epilubimin (1) and its reduction product, 15-dihydro-2-epilubimin (3). Their structures were deduced from 13C and 1H magnetic resonance data.

scholarly journals CHEMISTRY AND SYNTHESIS OF SOME DIHYDRO-2H-l,4-BENZOTHIAZINE DERIVATIVES

1966 ◽  
Vol 44 (11) ◽  
pp. 1247-1258 ◽  
Author(s):  
Raj Nandan Prasad ◽  
Karin Tietje
Keyword(s):  
Alkyl Halides ◽  
Reduction Product ◽  
Alkyl Derivatives ◽  
Reaction Proceeds ◽  
Thiazine Ring ◽  
Derivatives Of ◽  
Compound Xviii ◽  
Acyl Derivatives

The formation of 3-oxo-3,4-dihydro-2H-1,4-benzothiazine (IIIa) by cyclization of alkyl 2-haloacetamidophenyl sulfides (I) was investigated; it is proposed that the reaction proceeds via a six-membered sulfonium halide. The preparation of 4-alkyl derivatives of IIIa and of 4-alkyl and 4-acyl derivatives of its reduction product 3,4-dihydro-2H-1,4-benzothiazine (Va) is described. Acylation of Va was shown to proceed without opening of the thiazine ring. Preparation of the O-benzoyl, N-benzoyl, and O,N-dibenzoyl derivatives of 2-(β-hydroxyethyl-mercapto)aniline (VIII) has permitted clarification of the confusion in the literature with respect to the derivatives of Va and VIII. Compound XVIII, the 1,1-dioxide of IIIa, undergoes C-alkylation at the 2-position when treated with alkyl halides, rather than O-alkylation as previously suggested.

scholarly journals Dihydrodesoxystreptomycin, a New Reduction Product of Streptomycin

1956 ◽  
Vol 32 (1) ◽  
pp. 53-58 ◽  
Author(s):  
Hiroshi IKEDA ◽  
Kenji SHIROYANAGI ◽  
Hatsuko IKEDA ◽  
Kei-ichi TSUJI ◽  
Mitsuhiko KATAYAMA ◽  
...  
Keyword(s):  
Reduction Product

PSEUDACONITINE, AND THE STEREOCHEMICAL RELATIONSHIP OF THE HIGHLY OXYGENATED ACONITE ALKALOIDS

1963 ◽  
Vol 41 (6) ◽  
pp. 1485-1489 ◽  
Author(s):  
Y. Tsuda ◽  
Léo Marion
Keyword(s):  
Acetic Acid ◽  
Absolute Configuration ◽  
Lithium Aluminum Hydride ◽  
Aluminum Hydride ◽  
Reduction Product ◽  
Lithium Aluminum ◽  
Partial Hydrolysis ◽  
Previous Knowledge ◽  
Relationship Of ◽  
Hydrolysis Of

An alkaloid isolated from Aconitum spicatum Stapf has been found to be identical not only with the originally described pseudaconitine but also with 'α-pseudaconitine'. The product of the partial hydrolysis of the base, i.e., veratroylpseudaconine, is dextrorotatory, and not laevorotatory as recorded in the old literature. On heating, pseudaconitine undergoes pyrolysis, loses the elements of acetic acid, and gives rise to pyropseudaconitine. This substance, on treatment with lithium aluminum hydride, is converted to demethoxyisopyropseudaconine which is identical with the Wolff–Kishner reduction product of pyraconine. This correlation establishes that pseudaconitine and aconitine possess the same absolute configuration, which, in the light of previous knowledge, is extended also to indaconitine, delphinine, mesaconitine, and jesaconitine.

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