Electronic structure of metal carbonyl clusters. 2. An INDO investigation of tetra-, penta-, and hexanuclear nickel complexes

1984 ◽  
Vol 23 (2) ◽  
pp. 247-253 ◽  
Author(s):  
Piercarlo Fantucci ◽  
Gianfranco Pacchioni ◽  
Venanzio Valenti
Keyword(s):  
Electronic Structure ◽  
Metal Carbonyl ◽  
Nickel Complexes ◽  
Carbonyl Clusters ◽  
Structure Of Metal ◽  
Metal Carbonyl Clusters

Salts of Anionic Metal Carbonyl Clusters with Cryptand[2.2.2](Na+ ), DB-18-crown-6(Na+ ), and Paramagnetic Cp*2 Cr+ Cations Obtained by Reduction

2019 ◽  
Vol 645 (4) ◽  
pp. 472-483 ◽  
Author(s):  
Dmitri V. Konarev ◽  
Alexey V. Kuzmin ◽  
Roman S. Galkin ◽  
Salavat S. Khasanov ◽  
Rinat F. Kurbanov ◽  
...  
Keyword(s):  
Metal Carbonyl ◽  
Carbonyl Clusters ◽  
Metal Carbonyl Clusters

scholarly journals The Categorization and Structural Prediction of Transition Metal Carbonyl Clusters Using 14n Series Numerical Matrix

2016 ◽  
Vol 8 (1) ◽  
pp. 109
Author(s):  
Enos Masheija Rwantale Kiremire
Keyword(s):  
Transition Metal ◽  
Valence Electron ◽  
Metal Carbonyl ◽  
Electron Content ◽  
Constant Number ◽  
Carbonyl Clusters ◽  
Structural Prediction ◽  
Metal Carbonyl Clusters ◽  
The Matrix ◽  
Special Case

<p>A matrix table of valence electron content of carbonyl clusters has been created using the 14n-based series. The numbers so generated form an array of series which conform precisely with valence electron contents of carbonyl clusters. The renowned 18 electron rule is a special case of 14n+4 series. Similarly, the 16 electron rule is another special case of the 14n+2 series. Categorization of the carbonyl clusters using the matrix table of series has been demonstrated. The table is so organized that clusters numerically represented can easily be compared and analyzed. The numbers that are diagonally arranged from right to left represent capping series. The row from right to left represents a decrease in valence electron content with increase in cluster linkages. The variation of cluster shapes of constant number of skeletal elements especially four or more may be monitored or compared with the variation with the valence electron content.</p>

Synthesis, Characterization and Electrochemistry of Some Metal Carbonyl Clusters Derived from Ferrocenylethynylpyridine

2015 ◽  
Vol 26 (2) ◽  
pp. 461-471 ◽  
Author(s):  
Wai-Yeung Wong ◽  
Qingchen Dong ◽  
Suk-Ha Cheung ◽  
Pui-Ling Lau ◽  
Nian-Yong Zhu ◽  
...  
Keyword(s):  
Metal Carbonyl ◽  
Carbonyl Clusters ◽  
Metal Carbonyl Clusters

Supported Metal Carbonyl Clusters: Decomposition to Metals and Reactivity

1979 ◽  
pp. 579-601 ◽  
Author(s):  
R. Ugo ◽  
R. Psaro ◽  
G. M. Zanderighi ◽  
J. M. Basset ◽  
A. Theolier ◽  
...  
Keyword(s):  
Metal Carbonyl ◽  
Carbonyl Clusters ◽  
Metal Carbonyl Clusters ◽  
Supported Metal

Effect of Hydrogen Atoms on the Structures of Trinuclear Metal Carbonyl Clusters: Trinuclear Manganese Carbonyl Hydrides

2009 ◽  
Vol 48 (10) ◽  
pp. 4580-4591 ◽  
Author(s):  
Xian-mei Liu ◽  
Chao-yang Wang ◽  
Qian-shu Li ◽  
Yaoming Xie ◽  
R. Bruce King ◽  
...  
Keyword(s):  
Metal Carbonyl ◽  
Hydrogen Atoms ◽  
Carbonyl Clusters ◽  
Metal Carbonyl Clusters ◽  
Manganese Carbonyl
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