Electrochemical generation of sulfur-ligated molybdenum(II) and molybdenum(III) substrate binding sites. Preparation and crystal structures of [MoCl(S2CNEt2)2(Ph2PCH2CH2PPh2)][BF4] and [MoCl(S2CNEt2)2(PPh2Me)2][PF6] and the mechanism of their electrochemical reduction

Jonathan R. Dilworth; Bryan D. Neaves; Christopher J. Pickett; Joseph Chatt; Jon A. Zubieta

doi:10.1021/ic00166a009

Electrochemical generation of sulfur-ligated molybdenum(II) and molybdenum(III) substrate binding sites. Preparation and crystal structures of [MoCl(S2CNEt2)2(Ph2PCH2CH2PPh2)][BF4] and [MoCl(S2CNEt2)2(PPh2Me)2][PF6] and the mechanism of their electrochemical reduction

Inorganic Chemistry ◽

10.1021/ic00166a009 ◽

1983 ◽

Vol 22 (24) ◽

pp. 3524-3529 ◽

Cited By ~ 13

Author(s):

Jonathan R. Dilworth ◽

Bryan D. Neaves ◽

Christopher J. Pickett ◽

Joseph Chatt ◽

Jon A. Zubieta

Keyword(s):

Crystal Structures ◽

Electrochemical Reduction ◽

Binding Sites ◽

Substrate Binding ◽

Electrochemical Generation ◽

Substrate Binding Sites

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ChemInform Abstract: ELECTROCHEMICAL GENERATION OF SULFUR-LIGATED MOLYBDENUM(II) AND MOLYBDENUM(III) SUBSTRATE BINDING SITES. PREPARATION AND CRYSTAL STRUCTURES OF (MOCL(S2CNET2)2(PH2PCH2CH2PPH2))(BF4) AND (MOCL(S2CNET2)2(PPH2ME)2)(PF6) AND THE MECHANISM

Chemischer Informationsdienst ◽

10.1002/chin.198408248 ◽

1984 ◽

Vol 15 (8) ◽

Author(s):

J. R. DILWORTH ◽

B. D. NEAVES ◽

C. J. PICKETT ◽

J. CHATT ◽

J. A. ZUBIETA

Keyword(s):

Crystal Structures ◽

Binding Sites ◽

Substrate Binding ◽

Electrochemical Generation ◽

Substrate Binding Sites

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Generation of substrate-binding sites by electrochemical reduction of cis-[Fe2(cp)2(μ-SMe)2(MeCN)(L)]2+ (L = CO or MeCN). Reactivity of the sites toward CO and tBuNC. Crystal structure of [Fe2(cp)2(μ-SMe)2(CO)(MeCN)][BF4]2·CH2Cl2

Journal of the Chemical Society Dalton Transactions ◽

10.1039/a902793i ◽

1999 ◽

pp. 2371-2384 ◽

Cited By ~ 11

Author(s):

Pascale Madec ◽

Kenneth W. Muir ◽

François Y. Pétillon ◽

René Rumin ◽

Yannick Scaon ◽

...

Keyword(s):

Crystal Structure ◽

Electrochemical Reduction ◽

Binding Sites ◽

Substrate Binding ◽

Substrate Binding Sites

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Electrochemical Generation of Substrate-Binding Sites in Organometallic Complexes with the {Mo2(μ-SR)n Core. Electrosynthesis of Cyanide and Isocyanide Derivatives.

Molecular Electrochemistry of Inorganic, Bioinorganic and Organometallic Compounds ◽

10.1007/978-94-011-1628-2_3 ◽

1993 ◽

pp. 33-38 ◽

Cited By ~ 1

Author(s):

F. Gloaguen ◽

C. Le Floc’h ◽

F. Y. Pétillon ◽

P. Schollhammer ◽

J. Talarmin ◽

...

Keyword(s):

Binding Sites ◽

Substrate Binding ◽

Organometallic Complexes ◽

Electrochemical Generation ◽

Substrate Binding Sites

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Structures of lipoyl synthase reveal a compact active site for controlling sequential sulfur insertion reactions

Biochemical Journal ◽

10.1042/bj20140895 ◽

2014 ◽

Vol 464 (1) ◽

pp. 123-133 ◽

Cited By ~ 45

Author(s):

Jenny E. Harmer ◽

Martyn J. Hiscox ◽

Pedro C. Dinis ◽

Stephen J. Fox ◽

Andreas Iliopoulos ◽

...

Keyword(s):

Crystal Structures ◽

Active Site ◽

Binding Sites ◽

Substrate Binding ◽

Insertion Reactions ◽

Substrate Binding Sites ◽

Lipoyl Synthase

The biosynthesis of lipoyl cofactors requires two lipoyl synthase-mediated sulfur insertions. We report the crystal structures of a lipoyl synthase complexed with S-adenosylhomocysteine or 5′-methylthioadenosine. Models based on these structures identify likely substrate-binding sites.

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Crystal Structures ofPasteurella multocidaSialyltransferase Complexes with Acceptor and Donor Analogues Reveal Substrate Binding Sites and Catalytic Mechanism†,‡

Biochemistry ◽

10.1021/bi700346w ◽

2007 ◽

Vol 46 (21) ◽

pp. 6288-6298 ◽

Cited By ~ 78

Author(s):

Lisheng Ni ◽

Harshal A. Chokhawala ◽

Hongzhi Cao ◽

Ryan Henning ◽

Laura Ng ◽

...

Keyword(s):

Crystal Structures ◽

Binding Sites ◽

Catalytic Mechanism ◽

Substrate Binding ◽

Substrate Binding Sites

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Faculty Opinions recommendation of Identification of the TRiC/CCT substrate binding sites uncovers the function of subunit diversity in eukaryotic chaperonins.

Faculty Opinions – Post-Publication Peer Review of the Biomedical Literature ◽

10.3410/f.1046453.496422 ◽

2006 ◽

Author(s):

Amnon Horovitz

Keyword(s):

Binding Sites ◽

Substrate Binding ◽

Substrate Binding Sites

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Faculty Opinions recommendation of Bivalent phenethylamines as novel dopamine transporter inhibitors: evidence for multiple substrate-binding sites in a single transporter.

Faculty Opinions – Post-Publication Peer Review of the Biomedical Literature ◽

10.3410/f.718076922.793482351 ◽

2013 ◽

Author(s):

Robert Vandenberg

Keyword(s):

Dopamine Transporter ◽

Binding Sites ◽

Substrate Binding ◽

Multiple Substrate ◽

Substrate Binding Sites

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Covalent modification of substrate-binding sites of Escherichia coli ADP-glucose synthetase. Isolation and structural characterization of 8-azido-ADP-glucose-incorporated peptides.

Journal of Biological Chemistry ◽

10.1016/s0021-9258(17)36052-0 ◽

1986 ◽

Vol 261 (3) ◽

pp. 1058-1064

Author(s):

Y M Lee ◽

J Preiss

Keyword(s):

Escherichia Coli ◽

Structural Characterization ◽

Binding Sites ◽

Substrate Binding ◽

Covalent Modification ◽

Substrate Binding Sites

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Substrate-binding sites in acetylcholinesterase

Trends in Pharmacological Sciences ◽

10.1016/0165-6147(91)90621-x ◽

1991 ◽

Vol 12 ◽

pp. 422-426 ◽

Cited By ~ 26

Author(s):

Ferdinand Hucko ◽

Jaak Järv ◽

Christoph Weise

Keyword(s):

Binding Sites ◽

Substrate Binding ◽

Substrate Binding Sites

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Opposite stereospecificity of two tropinone reductases is conferred by the substrate-binding sites.

Journal of Biological Chemistry ◽

10.1016/s0021-9258(17)32627-3 ◽

1994 ◽

Vol 269 (16) ◽

pp. 11695-11698 ◽

Cited By ~ 1

Author(s):

K. Nakajima ◽

T. Hashimoto ◽

Y. Yamada

Keyword(s):

Binding Sites ◽

Substrate Binding ◽

Substrate Binding Sites

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