Crystal structure and magnetic properties of (.mu.-azido)-(.mu.-hydroxo)bis[(N,N,N'N'-tetramethylethylenediamine)copper(II)] perchlorate, a copper(II) dinuclear complex with a large ferromagnetic interaction

1983 ◽  
Vol 22 (20) ◽  
pp. 2877-2883 ◽  
Author(s):  
Olivier Kahn ◽  
Sonia Sikorav ◽  
Jacqueline Gouteron ◽  
Suzanne Jeannin ◽  
Yves Jeannin
Keyword(s):  
Crystal Structure ◽  
Magnetic Properties ◽  
Dinuclear Complex ◽  
Ferromagnetic Interaction

Crystal structure and magnetic properties of [Ni(terpy)(N3)2]2·2H2O, a nickel(II) dinuclear complex with ferromagnetic interaction

1990 ◽  
Vol 174 (2) ◽  
pp. 263-269 ◽  
Author(s):  
M.Isabel Arriortua ◽  
A.Roberto Cortes ◽  
Luis Lezam ◽  
Teofilo Rojo ◽  
Xabier Solans ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Magnetic Properties ◽  
Dinuclear Complex ◽  
Ferromagnetic Interaction

Structure and Magnetic Properties of a Dinuclear Complex with Iron(III) in Octahedral and Pyramidal Coordination

1994 ◽  
Vol 49 (9) ◽  
pp. 1239-1242 ◽  
Author(s):  
Ayhan Elmali ◽  
Yalcin Elerman ◽  
Ingrid Svoboda ◽  
Hartmut Fuess ◽  
Klaus Griesar ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Magnetic Properties ◽  
Magnetic Susceptibility ◽  
Magnetic Moment ◽  
Effective Magnetic Moment ◽  
Dinuclear Complex ◽  
Monoclinic Space Group ◽  
Temperature Dependent ◽  
Space Group ◽  
Binuclear Unit

[FeL(MeOH)Cl]2 (L = N-(2-hydroxyphenyl)salicylaldimine) was synthesized and its crystal structure determined, [C27H20N 2O5Cl2Fe2], monoclinic, space group P21/c, a = 9.528(1), b = 7.684(1), c = 18.365(2) Å, β = 109.83(1)°, V = 1264.8 Å3, Z = 2. Two identical [FeL(MeOH)Cl] fragments, related by an inversion centre, are combined by the two bridging O atoms, to form a binuclear unit. The iron(III) centers are separated by 3.163(2) Å and weakly antiferromagnetically coupled (J = -8 .0 (1 ) cm-1), which follows from temperature - dependent magnetic susceptibility measurements in the range 4.2 to 288 K. The effective magnetic moment per iron(III) is μeff = 7.4 μB at 288 K

Structure and Magnetic Properties of a Triply Oxygen. Bridged Dinuclear Ni(II) Complex

1996 ◽  
Vol 51 (8) ◽  
pp. 1132-1136 ◽  
Author(s):  
Yalcin Elerman ◽  
Mehmet Kabak ◽  
Ingrid Svoboda ◽  
Hartmut Fuess ◽  
Klaus Griesar ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Magnetic Properties ◽  
Magnetic Susceptibility ◽  
Dinuclear Complex ◽  
Temperature Dependent ◽  
Orthorhombic Space Group ◽  
Space Group ◽  
Oxygen Atoms

[Methylamino-(N,N′-1,3-propyl-disalicylaldiminato)-Ni(II)-bis-(N-methylsalicylaldiminato)- Ni(II)] was synthesized from the condensation of N,N′-1,3-propyl-disalicylaldimine, salicylaldehyde, methylaminohydrochloride, NaOH and Ni(CH3COO)2·H2O, and its crystal structure determined. [C34H37N5O4Ni2], orthorhombic, space group Pbca, a = 12.330( 1), b = 24.967(2), c = 20.616(2)Å, Z = 8. The dinuclear complex contains two octahedrally coordinated nickel atoms which are linked via three oxygen atoms with an average (Ni-O-Ni) angle of 87.2( 1)° and a Ni···Ni distance of 2.884(1)Å. The coordination is completed by three nitrogen atoms. The nickel(II) centers are ferromagnetically coupled (J = 11.5 cm-1) as derived from temperature-dependent magnetic susceptibility measurements in the range 5 - 280 K.

X-ray crystal structure, spectral and magnetic properties of a mixed-ligand dinuclear complex [Cu(Phen)(Sa)(ClO4)]2

Polyhedron ◽  
1995 ◽  
Vol 14 (5) ◽  
pp. 639-642 ◽  
Author(s):  
Ming Li ◽  
Jiang-Zhong Zou ◽  
Zheng Xu ◽  
Xiao-Zeng You ◽  
Xiao-Yin Huang
Keyword(s):  
Crystal Structure ◽  
Magnetic Properties ◽  
Mixed Ligand ◽  
Dinuclear Complex ◽  
X Ray

Unexpected Ferromagnetic Interaction in a New Tetranuclear Copper(II) Complex:  Synthesis, Crystal Structure, Magnetic Properties, and Theoretical Studies

2005 ◽  
Vol 44 (14) ◽  
pp. 5011-5020 ◽  
Author(s):  
Matilde Fondo ◽  
Ana M. García-Deibe ◽  
Monstserrat Corbella ◽  
Eliseo Ruiz ◽  
Javier Tercero ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Magnetic Properties ◽  
Theoretical Studies ◽  
Ferromagnetic Interaction
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