Synthesis and crystal structure of mercury-bridged transition-metal clusters: Hg[Ru3(CO)9(C2-tert-Bu)]2 and [(C2-tert-Bu)Ru3(CO)9HgMo(.eta.-C5H5)(CO)3]

1983 ◽  
Vol 22 (9) ◽  
pp. 1339-1344 ◽  
Author(s):  
Susan Ermer ◽  
Kevin King ◽  
Kenneth I. Hardcastle ◽  
Edward Rosenberg ◽  
Anna Maria Manotti Lanfredi ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Transition Metal ◽  
Metal Clusters ◽  
Transition Metal Clusters ◽  
Synthesis And Crystal Structure

Competitive adsorption of phenol and toluene onto silica-supported transition metal clusters for biofuel purification

2021 ◽  
Author(s):  
Saber Gueddida ◽  
Michael Badawi ◽  
Tejraj Aminabhavi ◽  
Sébastien Lebègue
Keyword(s):  
Transition Metal ◽  
Competitive Adsorption ◽  
Metal Clusters ◽  
Hydrocarbon Fuel ◽  
Energy Performance ◽  
Transition Metal Clusters ◽  
Gas Emissions ◽  
Toxic Gas

Biomass-based renewable hydrocarbon fuel is a complex mix that contains many oxygenating substances, in particular phenolics, which leads to adverse consequences such as reduced engine energy performance and increased toxic gas emissions.

Soluble lanthanide-transition-metal clusters Ln36Co12 as effective molecular electrocatalysts for water oxidation

2021 ◽  
Vol 57 (29) ◽  
pp. 3611-3614
Author(s):  
Rong Chen ◽  
Chao-Long Chen ◽  
Ming-Hao Du ◽  
Xing Wang ◽  
Cheng Wang ◽  
...  
Keyword(s):  
Transition Metal ◽  
Transition Metals ◽  
Synergistic Effect ◽  
Water Oxidation ◽  
Metal Clusters ◽  
Bond Formation ◽  
Transition Metal Clusters ◽  
Oxidation Activity ◽  
Acidic Conditions ◽  
Effective Water

The stable 48-metal Ln36Co12 clusters show an effective water oxidation activity under weak acidic conditions because of the synergistic effect between lanthanide and transition metals in O–O bond formation.

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