Addition compounds of alkali metal hydrides. 22. Convenient procedures for the preparation of lithium borohydride from sodium borohydride and borane-dimethyl sulfide in simple ether solvents

Herbert C. Brown; Yong Moon. Choi; S. Narasimhan

doi:10.1021/ic00140a014

Addition compounds of alkali metal hydrides. 22. Convenient procedures for the preparation of lithium borohydride from sodium borohydride and borane-dimethyl sulfide in simple ether solvents

Inorganic Chemistry ◽

10.1021/ic00140a014 ◽

1982 ◽

Vol 21 (10) ◽

pp. 3657-3661 ◽

Cited By ~ 21

Author(s):

Herbert C. Brown ◽

Yong Moon. Choi ◽

S. Narasimhan

Keyword(s):

Alkali Metal ◽

Sodium Borohydride ◽

Dimethyl Sulfide ◽

Metal Hydrides ◽

Lithium Borohydride ◽

Ether Solvents

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ChemInform Abstract: ADDITION COMPOUNDS OF ALKALI METAL HYDRIDES. 22. CONVENIENT PROCEDURES FOR THE PREPARATION OF LITHIUM BOROHYDRIDE FROM SODIUM BOROHYDRIDE AND BORANE-DIMETHYL SULFIDE IN SIMPLE ETHER SOLVENTS

Chemischer Informationsdienst ◽

10.1002/chin.198302031 ◽

1983 ◽

Vol 14 (2) ◽

Author(s):

H. C. BROWN ◽

Y. M. CHOI ◽

S. NARASIMHAN

Keyword(s):

Alkali Metal ◽

Sodium Borohydride ◽

Dimethyl Sulfide ◽

Metal Hydrides ◽

Lithium Borohydride ◽

Ether Solvents

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Convenient procedure for the conversion of sodium borohydride into lithium borohydride in simple ether solvents

Inorganic Chemistry ◽

10.1021/ic50226a091 ◽

1981 ◽

Vol 20 (12) ◽

pp. 4454-4456 ◽

Cited By ~ 39

Author(s):

Herbert C. Brown ◽

Yong Moon. Choi ◽

S. Narasimhan

Keyword(s):

Sodium Borohydride ◽

Lithium Borohydride ◽

Convenient Procedure ◽

Ether Solvents

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ChemInform Abstract: ADDITION COMPOUNDS OF ALKALI METAL HYDRIDES. 15. STERIC EFFECTS IN THE REACTION OF REPRESENTATIVE TRIALKYLBORANES WITH LITHIUM AND SODIUM HYDRIDES TO FORM THE CORRESPONDING TRIALKYLBOROHYDRIDES

Chemischer Informationsdienst ◽

10.1002/chin.197835282 ◽

1978 ◽

Vol 9 (35) ◽

Author(s):

H. C. BROWN ◽

S. KRISHNAMURTHY ◽

J. L. HUBBARD

Keyword(s):

Alkali Metal ◽

Metal Hydrides ◽

Steric Effects

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Quantum Monte Carlo and high-level ab initio molecular orbital investigation of dissociation channels of the positronic alkali-metal hydrides, [XH;e+] (X = Li, Na, and K)

The European Physical Journal D ◽

10.1140/epjd/e2014-40734-2 ◽

2014 ◽

Vol 68 (3) ◽

Cited By ~ 3

Author(s):

Yurika Yamada ◽

Yukiumi Kita ◽

Masanori Tachikawa ◽

Mike D. Towler ◽

Richard J. Needs

Keyword(s):

Monte Carlo ◽

Alkali Metal ◽

Ab Initio ◽

Molecular Orbital ◽

Quantum Monte Carlo ◽

Metal Hydrides ◽

High Level

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Addition compounds of alkali metal hydrides. 13. Reactions of alkali metal hydrides with trialkylboranes. Synthesis and dissociation of alkali metal trialkylborohydrides. Ethyl ether-organoborane as a reversible "solvent" for lithium hydride

Inorganic Chemistry ◽

10.1021/ic50175a015 ◽

1977 ◽

Vol 16 (9) ◽

pp. 2229-2233 ◽

Cited By ~ 13

Author(s):

Herbert C. Brown ◽

Albert. Khuri ◽

S. C. Kim

Keyword(s):

Alkali Metal ◽

Ethyl Ether ◽

Metal Hydrides ◽

Lithium Hydride

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Spectroscopy: V. the spectra of the alkali-metal hydrides

Reports on Progress in Physics ◽

10.1088/0034-4885/5/1/322 ◽

1938 ◽

Vol 5 (1) ◽

pp. 249-256 ◽

Cited By ~ 3

Author(s):

R W B Pearse

Keyword(s):

Alkali Metal ◽

Metal Hydrides

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A Convenient Preparation of Anhydrous Alkali Metal Thiocarboxylates

Zeitschrift für Naturforschung B ◽

10.1515/znb-1983-1210 ◽

1983 ◽

Vol 38 (12) ◽

pp. 1585-1590 ◽

Cited By ~ 11

Author(s):

Shinzi Kato ◽

Motohiro Oguri ◽

Masaru Ishida

Keyword(s):

Alkali Metal ◽

Physical Properties ◽

Metal Hydrides ◽

High Yields ◽

Convenient Preparation

A series of alkali metal thiocarboxylates (1-5) were found to be readily obtained in high yields by the reaction of thiocarboxylic acids with metal hydrides (LiH, NaH, KH), and rubidium or caesium acetates, respectively. Their physical properties were disclosed

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