Electrochemistry of liquid sulfur dioxide. A new synthesis of mercury hexafluoroarsenate (Hg3AsF6) and mercury hexafluoroantimonate (Hg3SbF6)

1982 ◽  
Vol 21 (4) ◽  
pp. 1692-1693 ◽  
Author(s):  
George E. Whitwell ◽  
Douglas C. Miller ◽  
James M. Burlitch
Keyword(s):  
Sulfur Dioxide ◽  
Liquid Sulfur ◽  
New Synthesis

ChemInform Abstract: Indium-Triflate-Catalyzed Ritter Reaction in Liquid Sulfur Dioxide.

ChemInform ◽  
2016 ◽  
Vol 47 (29) ◽  
Author(s):  
Daniels Posevins ◽  
Krista Suta ◽  
Maris Turks
Keyword(s):  
Sulfur Dioxide ◽  
Ritter Reaction ◽  
Liquid Sulfur ◽  
Indium Triflate

scholarly journals Reaction of α-Phenethyl Radical in Liquid Sulfur Dioxide

1969 ◽  
Vol 42 (10) ◽  
pp. 3001-3002 ◽  
Author(s):  
Masashi Iino ◽  
Tsutomu Enomoto ◽  
Niichiro Tokura
Keyword(s):  
Sulfur Dioxide ◽  
Liquid Sulfur

scholarly journals Eightfold Electrophilic Methylation of Octacyanotungstate [W(CN)8]4−/3−: Preparation of Homoleptic, Eight-coordinate Methylisocyanide Complexes [W(CNMe)8]4+/5+

2021 ◽  
Author(s):  
Malte Sellin ◽  
Susanne Margot Rupf ◽  
Ulrich Abram ◽  
Moritz Malischewski
Keyword(s):  
Sulfur Dioxide ◽  
Single Crystal ◽  
Epr Spectroscopy ◽  
X Ray Diffraction ◽  
Liquid Sulfur ◽  
Methyl Fluoride ◽  
X Ray ◽  
First Time ◽  
Ir And Raman ◽  
Methyl Triflate

Homoleptic eight-fold coordinated methylisocyanide complexes of W(IV) and W(V) have been prepared for the first time. The reaction of [NBu4]4[W(CN)8] with methyl triflate MeOTf gives [W(CNMe)8][OTf]4. The even stronger methylating mixture of methyl fluoride MeF and arsenic pentafluoride AsF5 in liquid sulfur dioxide SO2 is able to fully alkylate both [NBu4]4[W(CN)8] and [NBu4]3[W(CN)8]. The paramagnetic octakis(methylisocyanide)- tungsten(V) [W(CNMe)8][AsF6]5 is thermally highly unstable above −30 °C. All compounds have been characterized via single-crystal X-ray diffraction, IR and Raman, as well as NMR or EPR spectroscopy<br>

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