Electrochemical and ESR studies of molybdenum-sulfur donor complexes. One-electron reduction of [cis-bis(N,N-dialkyldithiocarbamato)dinitrosyl]molybdenum and -tungsten complexes

John R. Budge; John A. Broomhead; Peter D. W. Boyd

doi:10.1021/ic00133a032

Electrochemical and ESR studies of molybdenum-sulfur donor complexes. One-electron reduction of [cis-bis(N,N-dialkyldithiocarbamato)dinitrosyl]molybdenum and -tungsten complexes

Inorganic Chemistry ◽

10.1021/ic00133a032 ◽

1982 ◽

Vol 21 (3) ◽

pp. 1031-1036 ◽

Cited By ~ 12

Author(s):

John R. Budge ◽

John A. Broomhead ◽

Peter D. W. Boyd

Keyword(s):

Tungsten Complexes ◽

Electron Reduction ◽

Sulfur Donor ◽

And Tungsten

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ChemInform Abstract: ELECTROCHEMICAL AND ESR STUDIES OF MOLYBDENUM-SULFUR DONOR COMPLEXES. ONE-ELECTRON REDUCTION OF (CIS-BIS(N,N-DIALKYLDITHIOCARBAMATO)DINITROSYL)MOLYBDENUM AND -TUNGSTEN COMPLEXES

Chemischer Informationsdienst ◽

10.1002/chin.198224290 ◽

1982 ◽

Vol 13 (24) ◽

Author(s):

J. R. BUDGE ◽

J. A. BROOMHEAD ◽

P. D. W. BOYD

Keyword(s):

Tungsten Complexes ◽

Electron Reduction ◽

Sulfur Donor ◽

And Tungsten

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Molybdenum and tungsten complexes with metallo-ligands having sulfur donor atoms

Inorganica Chimica Acta ◽

10.1016/s0020-1693(00)80944-5 ◽

1990 ◽

Vol 168 (2) ◽

pp. 209-214 ◽

Cited By ~ 9

Author(s):

Kang Ding-Xue ◽

Maria Poor ◽

Elliott L. Blinn ◽

Paul M. Treichel

Keyword(s):

Tungsten Complexes ◽

Sulfur Donor ◽

And Tungsten

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Reactions leading to formation and cleavage of metal-metal and metal-.mu.-phosphido bonds in binuclear molybdenum and tungsten complexes. Structural analyses of W2(CO)8(.mu.-PPh2)2 and its two-electron reduction product, [Li(THF)3]2[W2(CO)8(.mu.-PPh2)2]

Journal of the American Chemical Society ◽

10.1021/ja00246a018 ◽

1987 ◽

Vol 109 (12) ◽

pp. 3617-3625 ◽

Cited By ~ 23

Author(s):

Shin Guang Shyu ◽

Mario Calligaris ◽

Giorgio Nardin ◽

Andrew Wojcicki

Keyword(s):

Reduction Product ◽

Tungsten Complexes ◽

Metal Metal ◽

Electron Reduction ◽

And Tungsten

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ChemInform Abstract: Molybdenum and Tungsten Complexes with Metallo-Ligands Having Sulfur Donor Atoms.

ChemInform ◽

10.1002/chin.199027292 ◽

1990 ◽

Vol 21 (27) ◽

Author(s):

D.-X. KANG ◽

M. POOR ◽

E. L. BLINN ◽

P. M. TREICHEL

Keyword(s):

Tungsten Complexes ◽

Sulfur Donor ◽

And Tungsten

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ChemInform Abstract: Reactions Leading to Formation and Cleavage of Metal-Metal and Metal-μ-Phosphido Bonds in Binuclear Molybdenum and Tungsten Complexes. Structural Analyses of W2(CO)8(μ-PPh2)2 and Its Two-Electron Reduction Product, (Li(THF)3)2(W2(CO)8

ChemInform ◽

10.1002/chin.198741280 ◽

1987 ◽

Vol 18 (41) ◽

Author(s):

S.-G. SHYU ◽

M. CALLIGARIS ◽

G. NARDIN ◽

A. WOJCICKI

Keyword(s):

Reduction Product ◽

Tungsten Complexes ◽

Metal Metal ◽

Electron Reduction ◽

And Tungsten

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Novel synthesis of reduced mixed-valence molybdenum and tungsten complexes by electrochemical oxidation of the seven-coordinate complexes MX(S2)(R2dtc)2 (M = Mo, X = O; M = W, X = O, S; R = alkyl; dtc = dithiocarbamate)

Inorganic Chemistry ◽

10.1021/ic00279a008 ◽

1988 ◽

Vol 27 (6) ◽

pp. 978-985 ◽

Cited By ~ 7

Author(s):

A. M. Bond ◽

J. A. Broomhead ◽

A. F. Hollenkamp

Keyword(s):

Electrochemical Oxidation ◽

Mixed Valence ◽

Tungsten Complexes ◽

Novel Synthesis ◽

And Tungsten

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Eine effiziente Synthesemethode für DiarylallenyIiden(pentacarbonyl)chrom- und -wolfram-Komplexe -Kristallstruktur von (CO)5Cr=C=C=CPh2 / An efficient Synthesis of Diarylallenylidene Pentacarbonyl Chromium and Tungsten Complexes - Crystal Structure of (CO)5Cr=C=C=CPh2

Zeitschrift für Naturforschung B ◽

10.1515/znb-1994-0909 ◽

1994 ◽

Vol 49 (9) ◽

pp. 1207-1214 ◽

Cited By ~ 18

Author(s):

Helmut Fischer ◽

David Reindl ◽

Gerhard Roth

Keyword(s):

Crystal Structure ◽

Structure Analysis ◽

Good Yield ◽

Efficient Synthesis ◽

X Ray ◽

Tungsten Complexes ◽

And Tungsten

An efficient synthesis of diarylallenylidene pentacarbonyl chromium and tungsten complexes is presented. Irradiation of M(CO)6 in THF affords (CO)sM[THF], Substitution of the THF ligand by diarylpropargylalcoholate and subsequent desoxygenation with COCF gives the title compounds in good yield. (The structure of diphenylallenylidene pentacarbonyl chromium has been determined by X-ray structure analysis

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ChemInform Abstract: Polynuclear Metal Complexes with Bridging Carbene or Carbyne Ligands. Part 92. Synthesis of Alkynylmethylidyne-Molybdenum and -Tungsten Complexes and Their Reactions with (Co2(CO)8) and (Mo2(CO)6(η-C5H5)2).

ChemInform ◽

10.1002/chin.199009283 ◽

1990 ◽

Vol 21 (9) ◽

Author(s):

I. J. HART ◽

A. F. HILL ◽

F. G. A. STONE

Keyword(s):

Metal Complexes ◽

Tungsten Complexes ◽

Polynuclear Metal Complexes ◽

And Tungsten

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Nature of M-(η2-H-SiR2) bonds in chromium, molybdenum and tungsten complexes [(η5-C5H5)(dmpe)M(η2-H-SiR2)] and [(η5-C5H5)(CO)2M(η2-H-SiMe2)]: A theoretical study

Polyhedron ◽

10.1016/j.poly.2013.03.034 ◽

2013 ◽

Vol 55 ◽

pp. 241-248 ◽

Cited By ~ 2

Author(s):

Krishna K. Pandey

Keyword(s):

Theoretical Study ◽

Tungsten Complexes ◽

And Tungsten

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Molybdenum and Tungsten Nitrosyl Complexes with Dithiocarbamate Ligands

Australian Journal of Chemistry ◽

10.1071/ch9791187 ◽

1979 ◽

Vol 32 (6) ◽

pp. 1187 ◽

Cited By ~ 7

Author(s):

JA Broomhead ◽

JR Budge

Keyword(s):

Photochemical Reactions ◽

Molybdenum Complexes ◽

Tungsten Complexes ◽

Nitrosyl Complexes ◽

Infrared Studies ◽

In Cis ◽

And Tungsten

Molybdenum and tungsten nitrosyl complexes with dithiocarbamato ligands have been prepared and characterized by analysis, and 1H n.m.r, and infrared studies. The molybdenum complexes are formulated as seven-coordinate species [Mo(NCO)L(S2CNEt2)2NO]- (L = Cl-, N3-, NCS-),{Mo(NCO)(S2CNEt2)2NO}2N2H4 and [Mo(NCO)B(S2CNEt2)2NO](B = NH3, pyridine). Likely stereochemistries are discussed. New tungsten complexes have been prepared by photochemical reactions of cis-[W(S2CNEt2)2(NO)2] to give [WL2(S2CNEt2)2NO]-, [WL(S2CNEt2)2(Me2SO)NO](L = NCO-, N3-, NCS-) and [W(NCO)(S2CNEt2)2(MeCONMe2)NO]. Assignments for the nitrosyl infrared bands in cis-[MO(S2CNEt2)2(NO)2] and [Mo(NCO)(S,CNEt2)2(Me2SO)NO] havebeen made by using 15NO labelled ligands.

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