Application of Resonance Raman Spectroscopy to Electronic Structure in Metal Complex Excited States. Excited-State Ordering and Electron Delocalization in Dipyrido[3,2-a:2',3'-c]phenazine (dppz): Complexes of Re(I) and Ru(II)

1995 ◽  
Vol 34 (26) ◽  
pp. 6421-6422 ◽  
Author(s):  
Jon R. Schoonover ◽  
W. Douglas Bates ◽  
Thomas J. Meyer
Keyword(s):  
Raman Spectroscopy ◽  
Electronic Structure ◽  
Excited State ◽  
Metal Complex ◽  
Excited States ◽  
Resonance Raman Spectroscopy ◽  
Resonance Raman ◽  
Electron Delocalization

scholarly journals Determination of the Lowest Excited State of Metal Complexes of Dipyrido[3, 2-a:2′,3′-c]Phenazine

1999 ◽  
Vol 19 (1-4) ◽  
pp. 287-289
Author(s):  
Mark R. Waterland ◽  
Keith C. Gordon
Keyword(s):  
Raman Spectroscopy ◽  
Excited State ◽  
Metal Complexes ◽  
Excited States ◽  
Copper Complexes ◽  
Resonance Raman Spectroscopy ◽  
Resonance Raman ◽  
Time Resolved ◽  
State Data

The nature of the lowest excited state of rhenium and copper complexes of dipyrido[3,2- a:2′ ,3′-c]phenazine (Dppz) has been determined using Resonance Raman, Time- Resolved Resonance Raman Spectroscopy and Spectroelectrochemistry. Comparison of spectroelectrochemical data and excited state data show that for the complexes studied no reduced ligand bands are observed in the excited state spectra thus the lowest excited states are all Ligand Centred in nature. The use of substituents at the 11 and/or 12 position of the ligand has no effect on the excited state ordering.

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