scholarly journals Interpretation of the Temperature Dependence of the EPR Spectrum of Cu2+-Doped (NH4)2[Cd(NH3)2(CrO4)2] and Crystal Structures of the High- and Low-Temperature Forms of the Host Lattice

1995 ◽  
Vol 34 (22) ◽  
pp. 5516-5523 ◽  
Author(s):  
Henrietta Headlam ◽  
Michael A. Hitchman ◽  
Horst Stratemeier ◽  
Jan M. M. Smits ◽  
Paul T. Beurskens ◽  
...  
1996 ◽  
Vol 442 ◽  
Author(s):  
J.-M. Spaeth ◽  
S. Greulich-Weber ◽  
M. März ◽  
E. N. Kalabukhova ◽  
S. N. Lukin

AbstractThe electronic structure of nitrogen donors in 6H-, 4H- and 3C-SiC is investigated by measuring the nitrogen hyperfine (hf) interactions with electron nuclear double resonance (ENDOR) and the temperature dependence of the hf split electron paramagnetic resonance (EPR) spectra. Superhyperfine (shf) interactions with many shells of 13C and 29Si were measured in 6H-SiC. The hf and shf interactions are discussed in the framework of effective mass theory. The temperature dependence is explained with the thermal occupation of the lowest valley-orbit split A1 and E states. It is proposed that the EPR spectra of P donors observed previously in neutron transmuted 6H-SiC at low temperature (<10K) and high temperature (>60K) are all due to substitutional P donors on the two quasi-cubic and hexagonal Si sites, whereby at low temperature the E state is occupied and at high temperature the A1 state. The low temperature spectra are thus thought not to be due to P-vacancy pair defects as proposed previously.


1974 ◽  
Vol 29 (1) ◽  
pp. 145-157 ◽  
Author(s):  
Tetsuhiko Tomiki ◽  
Takeo Miyata ◽  
Hirokazu Tsukamoto

Phenomenological and physical aspects of the intrinsic tail spectra of the alkalihalides are studied referring to the new results on the intrinsic tail spectra of KBr and KI and to the temperature dependences of the lowest-energy Γ-exciton peak of the sodium- and potassium-halides. Systematically analysing the temperature dependence of the steepness parameter σs (T) of the Urbach rule for these halides, it is found that the frequency factor has the value nearly equal to the acoustic phonon energy at X or L of each host lattice and the steepness constant σs0 becomes larger in passing from fluoride to iodide. This halogen dependence of σs0 is discussed in terms of the hole band-mass of the Γ8-level.


1999 ◽  
Vol 12 (5-8) ◽  
pp. 1097-1102 ◽  
Author(s):  
K.S. Kirn ◽  
Y.H. Seong ◽  
S.C. Yu ◽  
S.H. Han ◽  
H.J. Kim

1976 ◽  
Vol 6 (2) ◽  
pp. 119-121 ◽  
Author(s):  
Ronald E. Viola ◽  
Charles R. Hartzell ◽  
Joseph J. Villafranca

2003 ◽  
Vol 68 (7) ◽  
pp. 1233-1242 ◽  
Author(s):  
Orhan Turkoglu ◽  
Mustafa Soylak ◽  
Ibrahim Belenli

Chloro(phenyl)glyoxime, a vicinal dioxime, and its Ni(II), Cu(II) and Co(II) complexes were prepared. XRD patterns of the complexes point to similar crystal structures. IR and elemental analysis data revealed the 1:2 metal-ligand ratio in the complexes. The Co(II) complex is a dihydrate. Temperature dependence of electrical conductivity of the solid ligand and its complexes was measured in the temperature range 25-250 °C; it ranged between 10-14-10-6 Ω-1 cm-1 and increased with rising temperature. The activation energies were between 0.61-0.80 eV. The Co(II) complex has lower electric conductivity than the Ni(II) and Cu(II) complexes. This difference in the conductivity has been attributed to differences in the stability of the complexes.


1985 ◽  
Vol 119 (1) ◽  
pp. 225-232 ◽  
Author(s):  
Bernard Galiois ◽  
Jacques Gaultier ◽  
Christian Hauw ◽  
Daniel Chasseau ◽  
Alain Meresse ◽  
...  

2003 ◽  
Vol 236 (3) ◽  
pp. 640-644 ◽  
Author(s):  
G. N. Neilo ◽  
A. A. Prokhorov ◽  
S. N. Lykin ◽  
A. S. Karnachev ◽  
A. D. Prokhorov

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