A Donor−Acceptor−Donor Bridging Ligand in a Class III Mixed-Valence Complex

Peter J. Mosher; Glenn P. A. Yap; Robert J. Crutchley

doi:10.1021/ic001268u

A Donor−Acceptor−Donor Bridging Ligand in a Class III Mixed-Valence Complex

Inorganic Chemistry ◽

10.1021/ic001268u ◽

2001 ◽

Vol 40 (6) ◽

pp. 1189-1195 ◽

Cited By ~ 55

Author(s):

Peter J. Mosher ◽

Glenn P. A. Yap ◽

Robert J. Crutchley

Keyword(s):

Mixed Valence ◽

Class Iii ◽

Bridging Ligand ◽

Donor Acceptor ◽

Mixed Valence Complex

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Class III Delocalization in a Cyanide-Bridged Trimetallic Mixed-Valence Complex

Angewandte Chemie ◽

10.1002/ange.201307025 ◽

2013 ◽

Vol 126 (5) ◽

pp. 1317-1320 ◽

Cited By ~ 12

Author(s):

German E. Pieslinger ◽

Pablo Alborés ◽

Leonardo D. Slep ◽

Luis M. Baraldo

Keyword(s):

Mixed Valence ◽

Class Iii ◽

Mixed Valence Complex

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A pentaammineruthenium mixed-valence complex with 1,4-dicyanamido-2,3,5,6-tetrachlorobenzene dianion as bridging ligand: symmetry-attenuated electronic coupling between redox sites

Inorganic Chemistry ◽

10.1021/ic00344a005 ◽

1990 ◽

Vol 29 (19) ◽

pp. 3641-3644 ◽

Cited By ~ 10

Author(s):

Manuel A. S. Aquino ◽

Ann E. Bostock ◽

Robert J. Crutchley

Keyword(s):

Mixed Valence ◽

Electronic Coupling ◽

Bridging Ligand ◽

Redox Sites ◽

Mixed Valence Complex

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Strong Metal-Metal Coupling in a Dinuclear Terpyridinebipyridineruthenium Mixed-Valence Complex Incorporating the Bridging Ligand 1,4-Dicyanamidobenzene Dianion

Inorganic Chemistry ◽

10.1021/ic00122a016 ◽

1995 ◽

Vol 34 (18) ◽

pp. 4600-4604 ◽

Cited By ~ 27

Author(s):

Ali R. Rezvani ◽

Christopher E. B. Evans ◽

Robert J. Crutchley

Keyword(s):

Mixed Valence ◽

Bridging Ligand ◽

Metal Metal ◽

Mixed Valence Complex

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Class III Delocalization in a Cyanide-Bridged Trimetallic Mixed-Valence Complex

Angewandte Chemie International Edition ◽

10.1002/anie.201307025 ◽

2013 ◽

Vol 53 (5) ◽

pp. 1293-1296 ◽

Cited By ~ 36

Author(s):

German E. Pieslinger ◽

Pablo Alborés ◽

Leonardo D. Slep ◽

Luis M. Baraldo

Keyword(s):

Mixed Valence ◽

Class Iii ◽

Mixed Valence Complex

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Mixed valence complexes involving MM quadruple bonds (M=Mo or W)

Philosophical Transactions of The Royal Society A Mathematical Physical and Engineering Sciences ◽

10.1098/rsta.2007.2143 ◽

2007 ◽

Vol 366 (1862) ◽

pp. 101-112 ◽

Cited By ~ 13

Author(s):

Malcolm H Chisholm

Keyword(s):

Mixed Valence ◽

Electronic Coupling ◽

Organic Radical ◽

Radical Anions ◽

Class Iii ◽

Mixed Valency ◽

Bridging Ligand ◽

Quadruple Bond ◽

Redox Active ◽

Quadruple Bonds

The MM quadruple bond of configuration MM σ 2 π 4 δ 2 is redox active and in many ways ideally suited for studies of mixed valency when two or more such centres are linked by a bridging ligand. In this account, the mechanism of electronic coupling is examined for complexes of the type [L 3 M 2 bridgeM 2 L 3 ] 0/+ where L, a pivalate; bridge, a dicarboxylate or related ligand and M, Mo or W. The represented examples allow us to probe electronic factors close to the class II/III border and readily distinguish between electron and hole transfer in the superexchange mechanism. The potential for mixed valence organic radical anions mediated by the M 2 centre is also raised and one specific example of class III behaviour is described.

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The influence of cis/trans isomerism on the physical properties of a cyano-bridged dinuclear mixed valence complex

Journal of the Chemical Society Dalton Transactions ◽

10.1039/b110461f ◽

2002 ◽

pp. 1435 ◽

Cited By ~ 30

Author(s):

Paul V. Bernhardt ◽

Brendan P. Macpherson ◽

Manuel Martinez

Keyword(s):

Physical Properties ◽

Mixed Valence ◽

Mixed Valence Complex

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Design, synthesis and physico-chemical studies of a Co(II)/Co(III) mixed-valence complex: An experimental and DFT approach.

Journal of Molecular Structure ◽

10.1016/j.molstruc.2021.130384 ◽

2021 ◽

pp. 130384

Author(s):

Intissar Hamdi ◽

Noureddine Mhadhbi ◽

Noureddine Issaoui ◽

Andreas Roodt ◽

Mark M. Turnbull ◽

...

Keyword(s):

Mixed Valence ◽

Design Synthesis ◽

Physico Chemical ◽

Chemical Studies ◽

Mixed Valence Complex

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ChemInform Abstract: EXPERIMENTAL EVIDENCE FOR TRAPPED VALENCES IN THE MIXED-VALENCE COMPLEX μ-PYRAZINE-BIS(PENTAAMMINERUTHENIUM) TOSYLATE. ELECTRON PARAMAGNETIC RESONANCE, MAGNETIC SUSCEPTIBILITY, AND NUCLEAR MAGNETIC RESONANCE RESULTS

Chemischer Informationsdienst ◽

10.1002/chin.197838290 ◽

1978 ◽

Vol 9 (38) ◽

Author(s):

B. C. BUNKER ◽

R. S. DRAGO ◽

D. N. HENDRICKSON ◽

R. M. RICHMAN ◽

S. L. KESSELL

Keyword(s):

Nuclear Magnetic Resonance ◽

Electron Paramagnetic Resonance ◽

Magnetic Susceptibility ◽

Magnetic Resonance ◽

Experimental Evidence ◽

Mixed Valence ◽

Paramagnetic Resonance ◽

Electron Paramagnetic ◽

Mixed Valence Complex ◽

Nuclear Magnetic

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Elemental Carbon Chain Bridging Two Iron Centers: Syntheses and Spectroscopic Properties of [Cp(dppe)Fe-C4-FeCp(dppe)]n+.cntdot.n[PF6]-. X-ray Crystal Structure of the Mixed Valence Complex (n = 1)

Journal of the American Chemical Society ◽

10.1021/ja00132a013 ◽

1995 ◽

Vol 117 (27) ◽

pp. 7129-7138 ◽

Cited By ~ 262

Author(s):

Nathalie Le Narvor ◽

Loic Toupet ◽

Claude Lapinte

Keyword(s):

Crystal Structure ◽

Elemental Carbon ◽

Mixed Valence ◽

Spectroscopic Properties ◽

Carbon Chain ◽

X Ray ◽

Mixed Valence Complex

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Structure of a one-dimensional Br-bridged PtII-PtIV mixed-valence complex, catena-poly[bis(ethylenediamine)platinum(II,IV)-μ-bromo bis(hydrogensulfate)]

Acta Crystallographica Section C Crystal Structure Communications ◽

10.1107/s0108270192003457 ◽

1992 ◽

Vol 48 (11) ◽

pp. 1936-1939 ◽

Cited By ~ 5

Author(s):

N. Matsushita ◽

T. Taga ◽

I. Tsujikawa

Keyword(s):

Mixed Valence ◽

One Dimensional ◽

Mixed Valence Complex

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A Donor−Acceptor−Donor Bridging Ligand in a Class III Mixed-Valence Complex

Class III Delocalization in a Cyanide-Bridged Trimetallic Mixed-Valence Complex

A pentaammineruthenium mixed-valence complex with 1,4-dicyanamido-2,3,5,6-tetrachlorobenzene dianion as bridging ligand: symmetry-attenuated electronic coupling between redox sites

Strong Metal-Metal Coupling in a Dinuclear Terpyridinebipyridineruthenium Mixed-Valence Complex Incorporating the Bridging Ligand 1,4-Dicyanamidobenzene Dianion

Class III Delocalization in a Cyanide-Bridged Trimetallic Mixed-Valence Complex

Mixed valence complexes involving MM quadruple bonds (M=Mo or W)

The influence of cis/trans isomerism on the physical properties of a cyano-bridged dinuclear mixed valence complex

Design, synthesis and physico-chemical studies of a Co(II)/Co(III) mixed-valence complex: An experimental and DFT approach.

ChemInform Abstract: EXPERIMENTAL EVIDENCE FOR TRAPPED VALENCES IN THE MIXED-VALENCE COMPLEX μ-PYRAZINE-BIS(PENTAAMMINERUTHENIUM) TOSYLATE. ELECTRON PARAMAGNETIC RESONANCE, MAGNETIC SUSCEPTIBILITY, AND NUCLEAR MAGNETIC RESONANCE RESULTS

Elemental Carbon Chain Bridging Two Iron Centers: Syntheses and Spectroscopic Properties of [Cp*(dppe)Fe-C4-FeCp*(dppe)]n+.cntdot.n[PF6]-. X-ray Crystal Structure of the Mixed Valence Complex (n = 1)

Structure of a one-dimensional Br-bridged PtII-PtIV mixed-valence complex, catena-poly[bis(ethylenediamine)platinum(II,IV)-μ-bromo bis(hydrogensulfate)]

Elemental Carbon Chain Bridging Two Iron Centers: Syntheses and Spectroscopic Properties of [Cp(dppe)Fe-C4-FeCp(dppe)]n+.cntdot.n[PF6]-. X-ray Crystal Structure of the Mixed Valence Complex (n = 1)