Inner-Sphere Self-Exchange Electron Transfer in Low-Spin Co(III)-Co(II) Couples. Rate Determinations from 1H-NMR Line Broadening and a Simple Vibronic Model of the Reaction Coordinate

1995 ◽  
Vol 34 (18) ◽  
pp. 4572-4580 ◽  
Author(s):  
Carolyn L. Schwarz ◽  
John F. Endicott
Keyword(s):  
Electron Transfer ◽  
1H Nmr ◽  
Reaction Coordinate ◽  
Line Broadening ◽  
Inner Sphere

scholarly journals RuIII(edta) complexes as molecular redox catalysts in chemical and electrochemical reduction of dioxygen and hydrogen peroxide: inner-sphere versus outer-sphere mechanism

RSC Advances ◽  
2021 ◽  
Vol 11 (35) ◽  
pp. 21359-21366
Author(s):  
Debabrata Chatterjee ◽  
Marta Chrzanowska ◽  
Anna Katafias ◽  
Maria Oszajca ◽  
Rudi van Eldik
Keyword(s):  
Hydrogen Peroxide ◽  
Electron Transfer ◽  
Electrochemical Reduction ◽  
Molecular Oxygen ◽  
Outer Sphere ◽  
Transfer Processes ◽  
Edta Complexes ◽  
Inner Sphere ◽  
Electron Transfer Processes ◽  
Sphere Mechanism

[RuII(edta)(L)]2–, where edta4– =ethylenediaminetetraacetate; L = pyrazine (pz) and H2O, can reduce molecular oxygen sequentially to hydrogen peroxide and further to water by involving both outer-sphere and inner-sphere electron transfer processes.

Vibrational Dephasing along the Reaction Coordinate of an Electron Transfer Reaction

2021 ◽  
Vol 143 (36) ◽  
pp. 14511-14522
Author(s):  
Yusuke Yoneda ◽  
Bryan Kudisch ◽  
Shahnawaz Rafiq ◽  
Margherita Maiuri ◽  
Yutaka Nagasawa ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Transfer Reaction ◽  
Electron Transfer Reaction ◽  
Reaction Coordinate ◽  
Vibrational Dephasing

Mediated Inner‐Sphere Electron Transfer Induces Homogeneous Reduction of CO2 via Through‐Space Electronic Conjugation

2021 ◽  
Author(s):  
Shelby L. Hooe ◽  
Juan J. Moreno ◽  
Amelia G. Reid ◽  
Emma N. Cook ◽  
Charles Machan
Keyword(s):  
Electron Transfer ◽  
Homogeneous Reduction ◽  
Inner Sphere ◽  
Reduction Of Co2
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