Molecular and Electronic Structure of the Confacial Diosmium(III) Nonabromide Complex Anion. X-ray Crystallography of Rb3Os2Br9 and Direct Comparisons of [Os2Br9]3- with [Ru2Br9]3-

1994 ◽  
Vol 33 (18) ◽  
pp. 3986-3989 ◽  
Author(s):  
Stephen F. Gheller ◽  
Graham A. Heath ◽  
David C. R. Hockless ◽  
David G. Humphrey ◽  
John E. McGrady
Keyword(s):  
Electronic Structure ◽  
Complex Anion ◽  
X Ray ◽  
X Ray Crystallography ◽  
Molecular And Electronic Structure

Molekül-und Elektronenstruktur des Thioheteroanions [S2 WS2CoS2WS2]2- / Molecular and Electronic Structure of the Thiohetero Anion [S2WS2CoS2WS2]2-

1978 ◽  
Vol 33 (9) ◽  
pp. 978-982 ◽  
Author(s):  
A. Müller ◽  
N. Mohan ◽  
H. Bögge
Keyword(s):  
Molecular Structure ◽  
Electronic Structure ◽  
Single Crystal ◽  
Diffraction Data ◽  
Complex Anion ◽  
Crystal And Molecular Structure ◽  
X Ray Diffraction ◽  
X Ray ◽  
Data Space ◽  
Molecular And Electronic Structure

Abstract The crystal and molecular structure of [(C6H5)4P]2[Co(WS4)2] was determined from single crystal X-ray diffraction data (space group P21/c with a = 18.542(4), b = 15.443(2), c= 18.713(2) Å, β= 108.73(1)°, Z = 4). In the complex anion Co is coordinated by two bidentate chelating WS42- anions, with a nearly tetrahedral surrounding of Co. The bond lengths in the planar metal sulfur ring CoS2W are Co-S = 2.26 Å and W-S = 2.22 Å, while the terminal W-S bonds are 2.14 Å.

Molecular and electronic structure of an azidocobalt(iii) complex derived from X-ray crystallography, linear spectroscopy and quantum chemical calculations

2019 ◽  
Vol 21 (36) ◽  
pp. 20393-20402 ◽  
Author(s):  
Luis I. Domenianni ◽  
Reinhold Fligg ◽  
Annett Schäfermeier ◽  
Steffen Straub ◽  
Julia Beerhues ◽  
...  
Keyword(s):  
Electronic Structure ◽  
Fourier Transform ◽  
Infrared Spectroscopy ◽  
Quantum Chemical ◽  
Electronic Spectroscopy ◽  
X Ray Diffraction ◽  
Cationic Complex ◽  
X Ray ◽  
X Ray Crystallography ◽  
Molecular And Electronic Structure

X-ray diffraction, UV/Vis electronic spectroscopy and Fourier-transform infrared spectroscopy are used with DFT and CAS calculations to explore the molecular and electronic structure of the cationic complex (cyclam)(diazido)cobalt(iii).

X-ray spectral study of the influence of an outer-sphere cation on the electronic structure of a complex anion

1977 ◽  
Vol 18 (3) ◽  
pp. 453-459 ◽  
Author(s):  
L. N. Mazalov ◽  
�. A. Kravtsova ◽  
S. V. Zemskov ◽  
Yu. I. Nikonorov
Keyword(s):  
Electronic Structure ◽  
Spectral Study ◽  
Complex Anion ◽  
Outer Sphere ◽  
X Ray
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