Electrochemical and photophysical properties of new triazole-bridged heterobimetallic ruthenium-rhodium and ruthenium-iridium complexes

1992 ◽  
Vol 31 (17) ◽  
pp. 3518-3522 ◽  
Author(s):  
John H. Van Diemen ◽  
Ronald Hage ◽  
Jaap G. Haasnoot ◽  
Hans E. B. Lempers ◽  
Jan Reedijk ◽  
...  
2011 ◽  
Vol 64 (9) ◽  
pp. 1211 ◽  
Author(s):  
Bin Du ◽  
Si-Chun Yuan ◽  
Jian Pei

Two dendrimers, D1 and D2, containing the cationic iridium complexes (C1 and C2) as cores and truxene-functionalized chromophores as the branches, have been developed by a convergent synthetic strategy. The cationic complexes employ 3-(pyridin-2-yl)-1H-1,2,4-triazole and 2-(pyridin-2-yl)-benzimidazole derivatives as the ancillary ligands. To avoid the change in emission colour arising from the iridium complex, the conjugation between the dendron and the ligand is decoupled by separating them using the alkyl chain. An investigation of their photoluminescent features reveals that efficient energy transfer happens from the dendrons to the core in the solid state. Likewise, the charged dendritic structure is demonstrated to be an efficient method to improve the compatibility between the polar charged iridium complexes and typical hydrophobic hosts with the additional benefit of excellent solution processability. Both dendrimers exhibit strong solvatochromic behaviours in solvents and exclusive green and yellow-orange light in the solid state.


RSC Advances ◽  
2018 ◽  
Vol 8 (31) ◽  
pp. 17224-17236 ◽  
Author(s):  
Anastasia I. Solomatina ◽  
Shih-Hao Su ◽  
Maria M. Lukina ◽  
Varvara V. Dudenkova ◽  
Vladislav I. Shcheslavskiy ◽  
...  

Novel water-soluble iridium complexes with sulfonated diphosphine allow in vitro and in vivo lifetime hypoxia imaging.


2008 ◽  
Vol 55 (2) ◽  
pp. 439-448 ◽  
Author(s):  
Duo-Fong Huang ◽  
Tahsin J. Chow ◽  
Cheng-Yang Wu ◽  
Shih-Sheng Sun ◽  
Sheng-Heng Tsai ◽  
...  

2019 ◽  
Vol 43 (43) ◽  
pp. 16975-16980
Author(s):  
Yanling Si ◽  
Qinchao Wu ◽  
Yumeng Liu ◽  
Guochun Yang

The photophysical and charge transportation properties of POXD-based iridium complexes were investigated to unveil the microscopic mechanism behind experimental phenomena.


2009 ◽  
Vol 31 (6) ◽  
pp. 905-911 ◽  
Author(s):  
Liying Zhang ◽  
Bin Li ◽  
Linfang Shi ◽  
Wenlian Li

ChemPhysChem ◽  
2008 ◽  
Vol 9 (4) ◽  
pp. 634-640 ◽  
Author(s):  
Zhiwei Liu ◽  
Daobo Nie ◽  
Zuqiang Bian ◽  
Fangfang Chen ◽  
Bin Lou ◽  
...  

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